3D Porous Fused Aromatic Networks for High Performance Gas and Iodine Uptakes

dc.contributor.authorAhmad, Ishfaq
dc.contributor.authorNoh, Hyuk-Jun
dc.contributor.authorYu, Soo-Young
dc.contributor.authorJeon, Jong-Pil
dc.contributor.authorSun, Qikun
dc.contributor.authorMahmood, Javeed
dc.contributor.authorBaek, Jong-Beom
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.institutionCenter for Dimension-Controllable Organic Frameworks School of Energy and Chemical Engineering Ulsan National Institute of Science and Technology (UNIST) 50 UNIST Ulsan 44919 South Korea
dc.date.accepted2021-09-25
dc.date.accessioned2021-10-31T05:36:46Z
dc.date.available2021-10-31T05:36:46Z
dc.date.issued2021-10-24
dc.date.submitted2021-08-06
dc.description.abstractPorous organic networks (PONs) are an emerging class of organic materials with 2D and 3D architectures formed by covalent bonds between light elements, such as C, H, N, O, and B. Extensive efforts have been devoted to synthesizing thermally “stable” 3D PONs to realize their practical applications. Here, the design and synthesis are reported for two new 3D PONs with fused aromatic structures. The PONs structures are constructed by the double condensation reaction between tetrapodal octaamine and pyrenetetraketone (PTK) or hexaketocyclohexane (HKH) to produce PTK-PON (P-PON) or HKH-PON (H-PON), respectively. The prepared nitrogen-rich PONs show good thermal stabilities with specific surface areas of 873 m2 g−1 (P-PON) and 741 m2 g−1 (H-PON). Because of their relatively narrow pore dimensions (1.29 and 0.78 nm, respectively), the synthesized PONs exhibit high adsorption performance for small molecules such as carbon dioxide (CO2), hydrogen (H2), methane (CH4), and iodine (I2).
dc.description.sponsorshipThis work was supported by the Creative Research Initiative (CRI, 2014R1A3A2069102), BK21 Plus (10Z20130011057), Science Research Center (SRC, 2016R1A5A1009405) and Young Researcher (2019R1C1C1006650) Programs through the National Research Foundation (NRF) of Korea.
dc.eprint.versionPost-print
dc.identifier.citationAhmad, I., Noh, H., Yu, S., Jeon, J., Sun, Q., Mahmood, J., & Baek, J. (2021). 3D Porous Fused Aromatic Networks for High Performance Gas and Iodine Uptakes. Advanced Materials Interfaces, 2101373. doi:10.1002/admi.202101373
dc.identifier.doi10.1002/admi.202101373
dc.identifier.issn2196-7350
dc.identifier.issn2196-7350
dc.identifier.journalAdvanced Materials Interfaces
dc.identifier.pages2101373
dc.identifier.urihttp://hdl.handle.net/10754/672992
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/admi.202101373
dc.rightsArchived with thanks to Advanced Materials Interfaces
dc.rights.embargodate2022-10-24
dc.title3D Porous Fused Aromatic Networks for High Performance Gas and Iodine Uptakes
dc.typeArticle
display.details.left<span><h5>Embargo End Date</h5>2022-10-24<br><br><h5>Type</h5>Article<br><br><h5>Authors</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Ahmad, Ishfaq,equals">Ahmad, Ishfaq</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Noh, Hyuk-Jun,equals">Noh, Hyuk-Jun</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Yu, Soo-Young,equals">Yu, Soo-Young</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Jeon, Jong-Pil,equals">Jeon, Jong-Pil</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Sun, Qikun,equals">Sun, Qikun</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Mahmood, Javeed,equals">Mahmood, Javeed</a><br><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0003-4785-2326&spc.sf=dc.date.issued&spc.sd=DESC">Baek, Jong-Beom</a> <a href="https://orcid.org/0000-0003-4785-2326" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><br><h5>KAUST Department</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.department=Advanced Membranes and Porous Materials Research Center,equals">Advanced Membranes and Porous Materials Research Center</a><br><br><h5>Date</h5>2021-10-24<br><br><h5>Submitted Date</h5>2021-08-06</span>
display.details.right<span><h5>Abstract</h5>Porous organic networks (PONs) are an emerging class of organic materials with 2D and 3D architectures formed by covalent bonds between light elements, such as C, H, N, O, and B. Extensive efforts have been devoted to synthesizing thermally “stable” 3D PONs to realize their practical applications. Here, the design and synthesis are reported for two new 3D PONs with fused aromatic structures. The PONs structures are constructed by the double condensation reaction between tetrapodal octaamine and pyrenetetraketone (PTK) or hexaketocyclohexane (HKH) to produce PTK-PON (P-PON) or HKH-PON (H-PON), respectively. The prepared nitrogen-rich PONs show good thermal stabilities with specific surface areas of 873 m2 g−1 (P-PON) and 741 m2 g−1 (H-PON). Because of their relatively narrow pore dimensions (1.29 and 0.78 nm, respectively), the synthesized PONs exhibit high adsorption performance for small molecules such as carbon dioxide (CO2), hydrogen (H2), methane (CH4), and iodine (I2).<br><br><h5>Citation</h5>Ahmad, I., Noh, H., Yu, S., Jeon, J., Sun, Q., Mahmood, J., & Baek, J. (2021). 3D Porous Fused Aromatic Networks for High Performance Gas and Iodine Uptakes. Advanced Materials Interfaces, 2101373. doi:10.1002/admi.202101373<br><br><h5>Acknowledgements</h5>This work was supported by the Creative Research Initiative (CRI, 2014R1A3A2069102), BK21 Plus (10Z20130011057), Science Research Center (SRC, 2016R1A5A1009405) and Young Researcher (2019R1C1C1006650) Programs through the National Research Foundation (NRF) of Korea.<br><br><h5>Publisher</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.publisher=Wiley,equals">Wiley</a><br><br><h5>Journal</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.journal=Advanced Materials Interfaces,equals">Advanced Materials Interfaces</a><br><br><h5>DOI</h5><a href="https://doi.org/10.1002/admi.202101373">10.1002/admi.202101373</a><br><br><h5>Additional Links</h5>https://onlinelibrary.wiley.com/doi/10.1002/admi.202101373</span>
kaust.personMahmood, Javeed
orcid.authorAhmad, Ishfaq
orcid.authorNoh, Hyuk-Jun
orcid.authorYu, Soo-Young
orcid.authorJeon, Jong-Pil
orcid.authorSun, Qikun
orcid.authorMahmood, Javeed
orcid.authorBaek, Jong-Beom::0000-0003-4785-2326
orcid.id0000-0003-4785-2326
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