Demonstration of Photoelectrochemical-Type Photodetectors Using Seawater as Electrolyte for Portable and Wireless Optical Communication

Abstract
The emerging photoelectrochemical-type photodetector (PEC-PD), because of its unique device architecture by using an aqueous electrolyte, is naturally applicable in the pursuit of underwater optical communication without sophisticated device packaging and assembling. Unfortunately, the traditional PEC detecting process typically involves a large electrochemical workstation with long cables and wire connections for photo signal acquisition, which hinders its applications in wireless optical communication. In this work, an AlGaN nanowire-based self-powered PEC-PD is fabricated that uses seawater as an electrolyte, and then an optical communication system including the PEC-PD and a portable electrochemical workstation as the signal receiver for data communication is built. Essentially, the self-power PEC-PD shows a high responsivity of −15.5 mA W, a fast response/recovery time of ≈100 ms, and high stability operation in the seawater electrolyte. Foremost, the optical communication system shows high accuracy in wireless transmission of ASCII code signals in a seawater environment. Such a demonstration offers a new device architecture for possible under-seawater communication systems by leveraging the unique operation principle of photoelectrochemical devices in the future.

Citation
Luo, Y., Wang, D., Kang, Y., Liu, X., Fang, S., Memon, M. H., Yu, H., Zhang, H., Luo, D., Sun, X., Ooi, B. S., Gong, C., Xu, Z., & Sun, H. (2022). Demonstration of Photoelectrochemical-Type Photodetectors Using Seawater as Electrolyte for Portable and Wireless Optical Communication. Advanced Optical Materials, 2102839. Portico. https://doi.org/10.1002/adom.202102839

Acknowledgements
This work was funded by the National Key Research and Development Program of China (Grant No. 2018YFB1801904), the National Natural Science Foundation of China (Grant No. 52161145404, 61905236, 51961145110), the Fundamental Research Funds for the Central Universities (Grant No. WK2100230020), USTC Research Funds of the Double First-Class Initiative (Grant No. YD3480002002), and was partially carried out at the USTC Center for Micro and Nanoscale Research and Fabrication.

Publisher
Wiley

Journal
Advanced Optical Materials

DOI
10.1002/adom.202102839

Additional Links
https://onlinelibrary.wiley.com/doi/10.1002/adom.202102839

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