Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation

Abstract
Grafting of Zr(NMe2)4 on mesoporous silica SBA-15 afforded selectively well-defined surface species SiOZr(NMe2) (η2NMeCH2). 2D solid-state NMR (1H- 13C HETCOR, Multiple Quantum) experiments have shown a unique structural rearrangement occurring on the immobilised zirconium bis methylamido ligand. © The Royal Society of Chemistry 2013.

Citation
Eter, M. E., Hamzaoui, B., Abou-Hamad, E., Pelletier, J. D. A., & Basset, J.-M. (2013). Well-defined azazirconacyclopropane complexes supported on silica structurally determined by 2D NMR comparative elucidation. Chemical Communications, 49(41), 4616. doi:10.1039/c3cc40385h

Publisher
Royal Society of Chemistry (RSC)

Journal
Chemical Communications

DOI
10.1039/c3cc40385h

PubMed ID
23586075

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