Ethanol and water adsorption in methanol-derived ZIF-71

dc.contributor.authorLively, Ryan P.
dc.contributor.authorDose, Michelle E.
dc.contributor.authorThompson, Joshua A.
dc.contributor.authorMcCool, Benjamin A.
dc.contributor.authorChance, Ronald R.
dc.contributor.authorKoros, William J.
dc.contributor.institutionAlgenol Biofuels, , United States
dc.contributor.institutionGeorgia Institute of Technology, Atlanta, United States
dc.date.accessioned2016-02-25T13:17:12Z
dc.date.available2016-02-25T13:17:12Z
dc.date.issued2011
dc.description.abstractA room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.
dc.description.sponsorshipJ. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096.
dc.identifier.citationLively RP, Dose ME, Thompson JA, McCool BA, Chance RR, et al. (2011) Ethanol and water adsorption in methanol-derived ZIF-71. Chem Commun 47: 8667. Available: http://dx.doi.org/10.1039/c1cc12728d.
dc.identifier.doi10.1039/c1cc12728d
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.journalChemical Communications
dc.identifier.pmid21709911
dc.identifier.urihttp://hdl.handle.net/10754/598239
dc.publisherRoyal Society of Chemistry (RSC)
dc.titleEthanol and water adsorption in methanol-derived ZIF-71
dc.typeArticle
display.details.left<span><h5>Type</h5>Article<br><br><h5>Authors</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Lively, Ryan P.,equals">Lively, Ryan P.</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Dose, Michelle E.,equals">Dose, Michelle E.</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Thompson, Joshua A.,equals">Thompson, Joshua A.</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=McCool, Benjamin A.,equals">McCool, Benjamin A.</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Chance, Ronald R.,equals">Chance, Ronald R.</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Koros, William J.,equals">Koros, William J.</a><br><br><h5>KAUST Grant Number</h5>KUS-I1-011-21<br><br><h5>Date</h5>2011</span>
display.details.right<span><h5>Abstract</h5>A room temperature method for synthesizing zeolitic imidizolate framework 71 (ZIF-71) is described. The methanol-based synthesis results in >95% yields (based on Zn) and produces crystals with 70% greater surface area than reported earlier. Ethanol uptake into the ZIF compares favorably with a recent modeling-based study. Water uptake was significantly higher than model predictions. © The Royal Society of Chemistry 2011.<br><br><h5>Citation</h5>Lively RP, Dose ME, Thompson JA, McCool BA, Chance RR, et al. (2011) Ethanol and water adsorption in methanol-derived ZIF-71. Chem Commun 47: 8667. Available: http://dx.doi.org/10.1039/c1cc12728d.<br><br><h5>Acknowledgements</h5>J. A. Thompson and W. J. Koros gratefully acknowledge support for this work by award no. KUS-I1-011-21 made by King Abdullah University of Science and Technology (KAUST). This material is based upon work supported in part by the Department of Energy under Award Number DE-FOA-0000096.<br><br><h5>Publisher</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.publisher=Royal Society of Chemistry (RSC),equals">Royal Society of Chemistry (RSC)</a><br><br><h5>Journal</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.journal=Chemical Communications,equals">Chemical Communications</a><br><br><h5>DOI</h5><a href="https://doi.org/10.1039/c1cc12728d">10.1039/c1cc12728d</a><br><br><h5>PubMed ID</h5><a href="https://www.ncbi.nlm.nih.gov/pubmed/21709911">21709911</a></span>
kaust.grant.numberKUS-I1-011-21
orcid.authorLively, Ryan P.
orcid.authorDose, Michelle E.
orcid.authorThompson, Joshua A.
orcid.authorMcCool, Benjamin A.
orcid.authorChance, Ronald R.
orcid.authorKoros, William J.
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