Microporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis

dc.contributor.authorLuebke, Ryan
dc.contributor.authorWeselinski, Lukasz Jan
dc.contributor.authorBelmabkhout, Youssef
dc.contributor.authorChen, Zhijie
dc.contributor.authorWojtas, Łukasz
dc.contributor.authorEddaoudi, Mohamed
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.institutionDepartment of Chemistry, University of South Florida, 4202 East Fowler Avenue, Tampa, FL 33620, United States
dc.date.accessioned2015-08-03T11:47:18Z
dc.date.available2015-08-03T11:47:18Z
dc.date.issued2014-01-17
dc.date.published-online2014-01-17
dc.date.published-print2014-02-05
dc.description.abstractHere we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.
dc.description.sponsorshipAuthors gratefully acknowledge KAUST for funding.
dc.identifier.citationLuebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). Microporous Heptazine Functionalized (3,24)-Connected rht-Metal–Organic Framework: Synthesis, Structure, and Gas Sorption Analysis. Crystal Growth & Design, 14(2), 414–418. doi:10.1021/cg401802s
dc.identifier.doi10.1021/cg401802s
dc.identifier.issn15287483
dc.identifier.journalCrystal Growth & Design
dc.identifier.urihttp://hdl.handle.net/10754/563387
dc.publisherAmerican Chemical Society (ACS)
dc.relation.issupplementedbyDOI:10.5517/cc11q542
dc.titleMicroporous heptazine functionalized (3,24)-connected rht-metal-organic framework: Synthesis, structure, and gas sorption analysis
dc.typeArticle
display.details.left<span><h5>Type</h5>Article<br><br><h5>Authors</h5><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0002-1285-3321&spc.sf=dc.date.issued&spc.sd=DESC">Luebke, Ryan</a> <a href="https://orcid.org/0000-0002-1285-3321" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0003-4516-2727&spc.sf=dc.date.issued&spc.sd=DESC">Weselinski, Lukasz Jan</a> <a href="https://orcid.org/0000-0003-4516-2727" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0001-9952-5007&spc.sf=dc.date.issued&spc.sd=DESC">Belmabkhout, Youssef</a> <a href="https://orcid.org/0000-0001-9952-5007" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0001-9232-7382&spc.sf=dc.date.issued&spc.sd=DESC">Chen, Zhijie</a> <a href="https://orcid.org/0000-0001-9232-7382" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.author=Wojtas, Łukasz,equals">Wojtas, Łukasz</a><br><a href="https://repository.kaust.edu.sa/search?query=orcid.id:0000-0003-1916-9837&spc.sf=dc.date.issued&spc.sd=DESC">Eddaoudi, Mohamed</a> <a href="https://orcid.org/0000-0003-1916-9837" target="_blank"><img src="https://repository.kaust.edu.sa/server/api/core/bitstreams/82a625b4-ed4b-40c8-865a-d6a5225a26a4/content" width="16" height="16"/></a><br><br><h5>KAUST Department</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.department=Advanced Membranes and Porous Materials Research Center,equals">Advanced Membranes and Porous Materials Research Center</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.department=Chemical Science Program,equals">Chemical Science Program</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.department=Functional Materials Design, Discovery and Development (FMD3),equals">Functional Materials Design, Discovery and Development (FMD3)</a><br><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.department=Physical Science and Engineering (PSE) Division,equals">Physical Science and Engineering (PSE) Division</a><br><br><h5>Online Publication Date</h5>2014-01-17<br><br><h5>Print Publication Date</h5>2014-02-05<br><br><h5>Date</h5>2014-01-17</span>
display.details.right<span><h5>Abstract</h5>Here we synthesized the highly porous rht-MOF-9 as the first example of an rht-MOF having a polycyclic central core. This material was synthesized from a predesigned polyheterocyclic nitrogen-rich hexacarboxylate (tri-isophthalate) ligand, which serves as the 3-connected, trigonal molecular building block (MBB). When reacted under the proper conditions, this ligand, having three coplanar isophthalic acid moieties, codes for the in situ formation of the targeted 24-connected copper-based supermolecular building block (SBB) having rhombicuboctahedral geometry. This combination of a 24-connected building block linked through 3-connected nodes results in a novel material with the singular rht topology. The rht-MOF-9 compound exhibits promising H2 and CO2 adsorption properties in comparison to previously reported rht-MOFs. © 2014 American Chemical Society.<br><br><h5>Citation</h5>Luebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). Microporous Heptazine Functionalized (3,24)-Connected rht-Metal–Organic Framework: Synthesis, Structure, and Gas Sorption Analysis. Crystal Growth & Design, 14(2), 414–418. doi:10.1021/cg401802s<br><br><h5>Acknowledgements</h5>Authors gratefully acknowledge KAUST for funding.<br><br><h5>Publisher</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.publisher=American Chemical Society (ACS),equals">American Chemical Society (ACS)</a><br><br><h5>Journal</h5><a href="https://repository.kaust.edu.sa/search?spc.sf=dc.date.issued&spc.sd=DESC&f.journal=Crystal Growth & Design,equals">Crystal Growth & Design</a><br><br><h5>DOI</h5><a href="https://doi.org/10.1021/cg401802s">10.1021/cg401802s</a><br><br><h5>Relations</h5><b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Luebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). CCDC 974613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11q542. DOI: <a href="https://doi.org/10.5517/cc11q542">10.5517/cc11q542</a> HANDLE: <a href="http://hdl.handle.net/10754/624294">10754/624294</a></li></ul></span>
display.relations<b> Is Supplemented By:</b> <br/> <ul><li><i>[Dataset]</i> <br/> Luebke, R., Weseliński, Ł. J., Belmabkhout, Y., Chen, Z., Wojtas, Ł., & Eddaoudi, M. (2014). CCDC 974613: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/cc11q542. DOI: <a href="https://doi.org/10.5517/cc11q542">10.5517/cc11q542</a> HANDLE: <a href="http://hdl.handle.net/10754/624294">10754/624294</a></li></ul>
kaust.personLuebke, Ryan
kaust.personWeselinski, Lukasz Jan
kaust.personBelmabkhout, Youssef
kaust.personEddaoudi, Mohamed
kaust.personChen, Zhijie
orcid.authorLuebke, Ryan::0000-0002-1285-3321
orcid.authorWeselinski, Lukasz Jan::0000-0003-4516-2727
orcid.authorBelmabkhout, Youssef::0000-0001-9952-5007
orcid.authorChen, Zhijie::0000-0001-9232-7382
orcid.authorWojtas, Łukasz
orcid.authorEddaoudi, Mohamed::0000-0003-1916-9837
orcid.id0000-0003-1916-9837
orcid.id0000-0001-9232-7382
orcid.id0000-0001-9952-5007
orcid.id0000-0003-4516-2727
orcid.id0000-0002-1285-3321
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