Kinetics of Surfactant Desorption at an Air–Solution Interface

Type
Article

Authors
Morgan, C. E.
Breward, C. J. W.
Griffiths, I. M.
Howell, P. D.
Penfold, J.
Thomas, R. K.
Tucker, I.
Petkov, J. T.
Webster, J. R. P.

KAUST Grant Number
KUK-C1-013-04

Online Publication Date
2012-12-04

Print Publication Date
2012-12-18

Date
2012-12-04

Abstract
The kinetics of re-equilibration of the anionic surfactant sodium dodecylbenzene sulfonate at the air-solution interface have been studied using neutron reflectivity. The experimental arrangement incorporates a novel flow cell in which the subphase can be exchanged (diluted) using a laminar flow while the surface region remains unaltered. The rate of the re-equilibration is relatively slow and occurs over many tens of minutes, which is comparable with the dilution time scale of approximately 10-30 min. A detailed mathematical model, in which the rate of the desorption is determined by transport through a near-surface diffusion layer into a diluted bulk solution below, is developed and provides a good description of the time-dependent adsorption data. A key parameter of the model is the ratio of the depth of the diffusion layer, H c, to the depth of the fluid, Hf, and we find that this is related to the reduced Péclet number, Pe*, for the system, via Hc/Hf = C/Pe*1/2. Although from a highly idealized experimental arrangement, the results provide an important insight into the "rinse mechanism", which is applicable to a wide variety of domestic and industrial circumstances. © 2012 American Chemical Society.

Citation
Morgan CE, Breward CJW, Griffiths IM, Howell PD, Penfold J, et al. (2012) Kinetics of Surfactant Desorption at an Air–Solution Interface. Langmuir 28: 17339–17348. Available: http://dx.doi.org/10.1021/la304091g.

Acknowledgements
ISIS is acknowledged for the beam time on INTER and STFC and EPSRC for the CASE award for C.E.M. C.J.W.B. and I.M.G. acknowledge Award No. KUK-C1-013-04, made by King Abdullah University of Science and Technology (KAUST), for support. The authors acknowledge P. Carroll, G. Lawton, and W. Ranken at Unilever, Port Sunlight, for the construction of the flow cell.

Publisher
American Chemical Society (ACS)

Journal
Langmuir

DOI
10.1021/la304091g

PubMed ID
23167573

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