Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes

Abstract
Chiral, cationic NHC–iridium complexes are introduced as catalysts for the intramolecular hydroamination reaction of unactivated aminoalkenes.

Citation
Foster, D., Gao, P., Zhang, Z., Sipos, G., Sobolev, A. N., Nealon, G., … Dorta, R. (2021). Design, scope and mechanism of highly active and selective chiral NHC–iridium catalysts for the intramolecular hydroamination of a variety of unactivated aminoalkenes. Chemical Science. doi:10.1039/d0sc05884j

Acknowledgements
D. F. and P. G. thank UWA for a Research Training Postgraduate (RTP) Scholarship. G. S. thanks UWA for an International Postgraduate Research Scholarship (IPRS). R. D. thanks the Australian Research Council for generous funding (FT130101713).

Publisher
Royal Society of Chemistry (RSC)

Journal
Chemical Science

DOI
10.1039/d0sc05884j

Additional Links
http://xlink.rsc.org/?DOI=D0SC05884J

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