Revisiting the Activity Gap of Iridium Electrocatalysts for Acidic Water Oxidation.
KAUST DepartmentKAUST Catalysis Center and Division of Science and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia.
Chemical Science Program
KAUST Catalysis Center (KCC)
Physical Science and Engineering (PSE) Division
Embargo End Date2024-07-13
Permanent link to this recordhttp://hdl.handle.net/10754/693014
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AbstractIridium electrocatalysts have been extensively studied for the acidic water oxidation reaction (2H2O → O2 + 4H+ + 4e–, also known as the oxygen evolution reaction, OER) in recent years. However, the activity of different iridium catalysts, such as amorphous, crystalline, and metallic ones, varies significantly, and there is no common explanation for the origin of this difference. Here four types of iridium catalysts were selected as models and characterized by various techniques. The redox behavior of iridium catalysts and oxidation of hydrogen peroxide (in the form of OOH–) were applied to in situ probe the adsorption energy of oxygen reaction intermediates (*OH, *O, and *OOH) on iridium catalysts under the OER conditions. Structure–activity analysis suggested that the more optimal and broader distribution of adsorption energies on metallic iridium (iridium black) and its good conductivity are the origin of its highest activity among the four different iridium catalysts.
CitationGao, J., Tan, S. X., Liu, Y., Liu, B., & Huang, K.-W. (2023). Revisiting the Activity Gap of Iridium Electrocatalysts for Acidic Water Oxidation. The Journal of Physical Chemistry Letters, 6494–6505. https://doi.org/10.1021/acs.jpclett.3c01161
SponsorsThis research is supported by the Agency for Science, Technology and Research (A*STAR) under its Career Development Fund (C210812029) and Central Research Fund (SC22/22-11571U). This research is also supported by the National Research Foundation, Singapore, and Public Utilities Board, Singapore’s National Water Agency under its Competitive Funding for Water Research (CWR-2101-0029).
PublisherAmerican Chemical Society (ACS)
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