Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption

Jiang, Yu; Ma, Jiahui; Ran, Ziyu; Zhong, Huiqing; Zhang, Daohong; Hadjichristidis, Nikos

dc.contributor.author	Jiang, Yu
dc.contributor.author	Ma, Jiahui
dc.contributor.author	Ran, Ziyu
dc.contributor.author	Zhong, Huiqing
dc.contributor.author	Zhang, Daohong
dc.contributor.author	Hadjichristidis, Nikos
dc.date.accessioned	2022-09-11T06:41:42Z
dc.date.available	2022-09-11T06:41:42Z
dc.date.issued	2022-09-09
dc.identifier.citation	Jiang, Y., Ma, J., Ran, Z., Zhong, H., Zhang, D., & Hadjichristidis, N. (2022). Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption. Angewandte Chemie. Portico. https://doi.org/10.1002/ange.202208516
dc.identifier.issn	0044-8249
dc.identifier.issn	1521-3757
dc.identifier.doi	10.1002/ange.202208516
dc.identifier.doi	10.1002/anie.202208516
dc.identifier.uri	http://hdl.handle.net/10754/681120
dc.description.abstract	Versatile strategy for smart fluorescent materials is lacking due to their diverse responding mechanisms and incompatibility of responsive behaviors. Herein presents an adaptable strategy toward multi-stimuli-responsive fluorescent material with stage-by-stage responsive behavior by blending linear polymers modified with different stimulus-responsive moieties and AIE cross-linker. Under stimuli, the linear polymer can cross-link with the cross-linker to form networks, which intrinsically restrict the intramolecular rotation of the AIE molecule to induce strong emission. A unified stimuli-responsive mechanism is involved in that various stimuli are transferred through the organized "stimulus-crosslink-emission" process. This strategy ensures the compatibility of different stimuli-responses and the adjustability of stimulus-response behavioral logic. These multi-stimuli-responsive fluorescent materials have exhibited strong accessibility and adaptability for information encryption.
dc.description.sponsorship	We gratefully acknowledge financial support from the National Natural Science Foundation of China (52103016,51873233), Innovation Group of National Ethnic Affairs Commission of China (MZR20006), and the South-Central Minzu University (YZZ19002). N.H. acknowledges the support of KAUST.
dc.publisher	Wiley
dc.relation.url	https://onlinelibrary.wiley.com/doi/10.1002/ange.202208516
dc.rights	This is an accepted manuscript version of a paper before final publisher editing and formatting. Archived with thanks to Wiley. The version of record is available from Angewandte Chemie.
dc.title	Versatile Strategy for Multi-Stimuli-Responsive Fluorescent Material Based on Cross-Linking-Induced Emission. Application in Encryption
dc.type	Article
dc.contributor.department	Chemical Science Program
dc.contributor.department	KAUST Catalysis Center (KCC)
dc.contributor.department	Physical Science and Engineering (PSE) Division
dc.contributor.department	Polymer Synthesis Laboratory
dc.identifier.journal	Angewandte Chemie
dc.rights.embargodate	2023-09-09
dc.eprint.version	Post-print
dc.contributor.institution	Key Laboratory of Catalysis and Energy Materials Chemistry of Ministry of Education &Hubei Key Laboratory of Catalysis and Materials Science, Hubei R&D Center of Hyperbranched Polymers Synthesis and Applications, South-CentralMinzu University, Wuhan430074, People's Republic of China.
kaust.person	Hadjichristidis, Nikos