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    First-Generation Organic Reaction Intermediates in Zeolite Chemistry and Catalysis

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    Type
    Article
    Authors
    Gong, Xuan
    Caglayan, Mustafa cc
    Ye, Yiru cc
    Liu, Kun
    Gascon, Jorge cc
    Chowdhury, Abhishek Dutta cc
    KAUST Department
    Chemical Engineering Program
    Physical Science and Engineering (PSE) Division
    KAUST Catalysis Center (KCC)
    Date
    2022-08-10
    Embargo End Date
    2023-08-10
    Permanent link to this record
    http://hdl.handle.net/10754/680266
    
    Metadata
    Show full item record
    Abstract
    Zeolite chemistry and catalysis are expected to play a decisive role in the next decade(s) to build a more decentralized renewable feedstock-dependent sustainable society owing to the increased scrutiny over carbon emissions. Therefore, the lack of fundamental and mechanistic understanding of these processes is a critical "technical bottleneck" that must be eliminated to maximize economic value and minimize waste. We have identified, considering this objective, that the chemistry related to the first-generation reaction intermediates (i.e., carbocations, radicals, carbenes, ketenes, and carbanions) in zeolite chemistry and catalysis is highly underdeveloped or undervalued compared to other catalysis streams (e.g., homogeneous catalysis). This limitation can often be attributed to the technological restrictions to detect such "short-lived and highly reactive" intermediates at the interface (gas-solid/solid-liquid); however, the recent rise of sophisticated spectroscopic/analytical techniques (including under in situ/operando conditions) and modern data analysis methods collectively compete to unravel the impact of these organic intermediates. This comprehensive review summarizes the state-of-the-art first-generation organic reaction intermediates in zeolite chemistry and catalysis and evaluates their existing challenges and future prospects, to contribute significantly to the "circular carbon economy" initiatives.
    Citation
    Gong, X., Çağlayan, M., Ye, Y., Liu, K., Gascon, J., & Dutta Chowdhury, A. (2022). First-Generation Organic Reaction Intermediates in Zeolite Chemistry and Catalysis. Chemical Reviews. https://doi.org/10.1021/acs.chemrev.2c00076
    Sponsors
    We acknowledge the financial support from the National Natural Science Foundation of China (NSFC) (grant no. 22050410276 to A.D.C.), the start-up research grant from Wuhan University (China), King Abdullah University of Science and Technology (Saudi Arabia), and the China Postdoctoral Science Foundation (2021M702515 and 2022T150493 to X.G.).
    Publisher
    American Chemical Society (ACS)
    Journal
    Chemical Reviews
    DOI
    10.1021/acs.chemrev.2c00076
    PubMed ID
    35947790
    Additional Links
    https://pubs.acs.org/doi/10.1021/acs.chemrev.2c00076
    ae974a485f413a2113503eed53cd6c53
    10.1021/acs.chemrev.2c00076
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Engineering Program; KAUST Catalysis Center (KCC)

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