Separation of ethyltoluene isomers by nonporous adaptive crystals of perethylated and perbromoethylated pillararenes
KAUST DepartmentChemical Science Program
Advanced Membranes and Porous Materials Research Center
Physical Science and Engineering (PSE) Division
KAUST Grant NumberOSR-2019-CRG8-4032
Embargo End Date2024-05-10
Permanent link to this recordhttp://hdl.handle.net/10754/677932
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AbstractThe separation of p-ethyltoluene (PET) and m-ethyltoluene (MET) is one of the most challenging steps to isolate PET from C9 aromatic compounds due to their very close boiling points. Many kinds of separation methods have been developed, but they involve low efficiency and great energy consumption. Herein, we investigate the adsorptive properties of perethylated pillararene (EtP5), perethylated pillararene (EtP6), perbromoethylated pillararene (BrP5) and perbromoethylated pillararene (BrP6) for ethyltoluene isomers. Results show that EtP6 and BrP5 crystals separate PET from a PET/MET equimolar mixture with purities of 95.4% and 92.0%, respectively. Both of them show no decrease in selectivity upon cycling for 5 times. Relatively, EtP5 and BrP6 crystals fail in this separation due to poor PET capture ability and low selectivity, respectively.
CitationWang, M., Fang, S., Yang, S., Li, Q., Khashab, N. M., Zhou, J., & Huang, F. (2022). Separation of ethyltoluene isomers by nonporous adaptive crystals of perethylated and perbromoethylated pillararenes. Materials Today Chemistry, 24, 100919. https://doi.org/10.1016/j.mtchem.2022.100919
SponsorsSupported by National Key Research and Development Program of China (2021YFA0910100), National Natural Science Foundation of China (22035006), Zhejiang Provincial Natural Science Foundation of China (LD21B020001), the Starrys Night Science Fund of Zhejiang University Shanghai Institute for Advanced Study (SN-ZJU-SIAS-006), and the King Abdullah University of Science and Technology Office of Sponsored Research (OSR-2019-CRG8-4032).
JournalMaterials Today Chemistry