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dc.contributor.authorCerrillo, Jose L.
dc.contributor.authorMorlanes, Natalia Sanchez
dc.contributor.authorKulkarni, Shekhar Rajabhau
dc.contributor.authorRealpe, Natalia
dc.contributor.authorRamírez, Adrian
dc.contributor.authorKatikaneni, Sai P.
dc.contributor.authorPaglieri, Stephen N.
dc.contributor.authorLee, Kunho
dc.contributor.authorHarale, Aadesh
dc.contributor.authorSolami, Bandar
dc.contributor.authorJamal, Aqil
dc.contributor.authorSarathy, Mani
dc.contributor.authorCastaño, Pedro
dc.contributor.authorGascon, Jorge
dc.date.accessioned2022-01-25T12:32:56Z
dc.date.available2022-01-25T12:32:56Z
dc.date.issued2021-12-24
dc.date.submitted2021-10-28
dc.identifier.citationCerrillo, J. L., Morlanés, N., Kulkarni, S. R., Realpe, N., Ramírez, A., Katikaneni, S. P., … Gascon, J. (2021). High purity, self-sustained, pressurized hydrogen production from ammonia in a catalytic membrane reactor. Chemical Engineering Journal, 134310. doi:10.1016/j.cej.2021.134310
dc.identifier.issn1385-8947
dc.identifier.doi10.1016/j.cej.2021.134310
dc.identifier.urihttp://hdl.handle.net/10754/675133
dc.description.abstractThe combination of catalytic decomposition of ammonia and in situ separation of hydrogen holds great promise for the use of ammonia as a clean energy carrier. However, finding the optimal catalyst – membrane pair and operation conditions have proved challenging. Here, we demonstrate that cobalt-based catalysts for ammonia decomposition can be efficiently used together with a Pd-Au based membrane to produce high purity hydrogen at elevated pressure. Compared to a conventional packed bed reactor, the membrane reactor offers several operational advantages that result in energetic and economic benefits. The robustness and durability of the combined system has been demonstrated for>1000 h on stream, yielding a very pure hydrogen stream (>99.97 % H2) and recovery (>90 %). When considering the required hydrogen compression for storage/utilization and environmental issues, the combined system offers the additional advantage of production of hydrogen at moderate pressures along with full ammonia conversion. Altogether, our results demonstrate the possibility of deploying high pressure (350 bar) hydrogen generators from ammonia with H2 efficiencies of circa 75% without any external energy input and/or derived CO2 emissions.
dc.description.sponsorshipThe authors gratefully acknowledge the financial support provided by Saudi Aramco, and the resources and facilities provided by the King Abdullah University of Science and Technology. N.M. and J.G. conceived this work. J.L.C and N.M. designed, characterized and conducted synthesis and catalytic experiments. N.R. and S.R.K. performed control regime studies. A.R. performed the technology simulation comparison and provided experimental support. J.G. P.C. and S.M.S. provided revision suggestions. J.L.C and N.M. wrote the original draft of the manuscript. All authors have given the approval to the final version of the manuscript.
dc.publisherElsevier BV
dc.relation.urlhttps://linkinghub.elsevier.com/retrieve/pii/S1385894721058824
dc.rightsThis is an open access article under the CC BY license.
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.titleHigh purity, self-sustained, pressurized hydrogen production from ammonia in a catalytic membrane reactor
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentClean Combustion Research Center
dc.identifier.journalChemical Engineering Journal
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionCarbon Management R&D Division, Research and Development Center, Saudi Aramco, Dhahran 31311, Saudi Arabia
dc.identifier.volume431
dc.identifier.pages134310
kaust.personCerrillo, Jose L.
kaust.personMorlanes, Natalia Sanchez
kaust.personKulkarni, Shekhar Rajabhau
kaust.personRealpe, Natalia
kaust.personRamírez, Adrian
kaust.personSarathy, Mani
kaust.personCastano, Pedro
kaust.personGascon, Jorge
dc.date.accepted2021-10-20
dc.identifier.eid2-s2.0-85121919103
refterms.dateFOA2022-01-25T12:34:45Z
dc.date.published-online2021-12-24
dc.date.published-print2021-12


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