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dc.contributor.authorWang, Ying
dc.contributor.authorZhu, Linlin
dc.contributor.authorChen, Wenhao
dc.contributor.authorZhou, Zhi
dc.contributor.authorZhang, Zhen
dc.contributor.authorHadjichristidis, Nikos
dc.date.accessioned2022-01-18T13:21:11Z
dc.date.available2022-01-18T13:21:11Z
dc.date.issued2022-01-05
dc.date.submitted2021-10-12
dc.identifier.citationWang, Y., Zhu, L., Chen, W., Zhou, Z., Zhang, Z., & Hadjichristidis, N. (2022). Bimetallic Cu(I)/Rh(II) Relay Catalysis for Multicomponent Polymerization through Carbene Intermediates. Macromolecules. doi:10.1021/acs.macromol.1c02130
dc.identifier.issn0024-9297
dc.identifier.issn1520-5835
dc.identifier.doi10.1021/acs.macromol.1c02130
dc.identifier.urihttp://hdl.handle.net/10754/675032
dc.description.abstractA highly efficient and multicomponent step-growth polymerization via carbene intermediates is established by bimetallic relay catalytic systems. This strategy, which provides a facile synthetic pathway to novel luminescent polysulfonamides, could overcome the limitation on the choice of carbene monomers and their difficulty in achieving high-molecular-weight polymers. The polymerizations occur through a tandem Cu(I)-catalyzed click reaction and an Rh(II)-catalyzed carbene 1,3-insertion reaction. The high reactivity of Rh(II)-bonded imino carbene intermediates allows a wide range of reactivity with various carboxylic acids, alcohols, and phenols. These results point to an untapped pathway for the use of metal carbene intermediates to construct new macromolecules.
dc.description.sponsorshipThis work is financially supported by the National Natural Science Foundation of China (21801049) and the Opening Project of Key Laboratory of Polymer Processing Engineering (South China University of Technology), and Ministry of Education (KFKT2006). N.H. acknowledges the support of King Abdullah University of Science and Technology.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.macromol.1c02130
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Macromolecules, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.macromol.1c02130.
dc.titleBimetallic Cu(I)/Rh(II) Relay Catalysis for Multicomponent Polymerization through Carbene Intermediates
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalMacromolecules
dc.rights.embargodate2023-01-05
dc.eprint.versionPost-print
dc.contributor.institutionSchool of Chemical Engineering and Light Industry, Guangdong University of Technology, Guangzhou 510006, P. R. China
dc.contributor.institutionKey Laboratory of Polymer Processing Engineering (South China University of Technology), Ministry of Education, Guangzhou 510641, P. R. China
kaust.personHadjichristidis, Nikos
dc.date.accepted2021-11-17


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