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dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorYao, Changguang
dc.contributor.authorZhang, Tonghuan
dc.contributor.authorGoncalves, Theo
dc.date.accessioned2022-01-05T06:54:47Z
dc.date.available2022-01-05T06:54:47Z
dc.date.issued2022
dc.identifier.citationHuang, K.-W., Yao, C., Zhang, T., & Goncalves, T. P. (2022). Selective benzylic Csp3–H bond activations mediated by a phosphorus–nitrogen PN3P-nickel complex. Chemical Communications. doi:10.1039/d1cc06507f
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.doi10.1039/d1cc06507f
dc.identifier.urihttp://hdl.handle.net/10754/674872
dc.description.abstractIn contrast to the typical Csp2−H activation, a PN3P-Nickel complex chemoselectively cleaved the benzylic Csp3–H bond of toluene in the presence of KHMDS, presumably via an in situ generated potassium benzyl intermediate. Under similar conditions, CO underwent deoxygenation to afford the corresponding nickel cyano complex, and ethylbenzene was dehydrogenated to give styrene and a nickel hydride compound. 2,6-xylyl isocyanide was transformed into an unprecedented indolyl complex, likely by trapping the activated benzyl species with a isocyanide moiety.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2022/CC/D1CC06507F
dc.relation.urlhttps://pubs.rsc.org/en/content/articlepdf/2022/cc/d1cc06507f
dc.relation.urlhttps://pubs.rsc.org/en/content/articlepdf/2022/cc/d1cc06507f
dc.rightsArchived with thanks to Royal Society of Chemistry (RSC) under a Creative Commons license, details at: http://creativecommons.org/licenses/by-nc/3.0/
dc.rightsThis file is an open access version redistributed from: https://pubs.rsc.org/en/content/articlepdf/2022/cc/d1cc06507f
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.titleSelective benzylic Csp3–H bond activations mediated by a phosphorus–nitrogen PN3P-nickel complex
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentKAUST Catalysis Center and Division of Physical Sciences and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Saudi Arabia.
dc.identifier.journalChemical Communications
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionSchool of Resource, Environmental and Chemical Engineering, Nanchang University, Nanchang 330031, Jiangxi, China
dc.contributor.institutionLab of Computational Chemistry and Drug Design, State Key Laboratory of Chemical Oncogenomics, Peking University, Shenzhen Graduate School Shenzhen 518055, China
kaust.personHuang, Kuo-Wei
kaust.personYao, Changguang
kaust.personZhang, Tonghuan
kaust.personGoncalves, Theo
refterms.dateFOA2022-09-21T11:11:29Z


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Archived with thanks to Royal Society of Chemistry (RSC) under a Creative Commons license, details at: http://creativecommons.org/licenses/by-nc/3.0/
Except where otherwise noted, this item's license is described as Archived with thanks to Royal Society of Chemistry (RSC) under a Creative Commons license, details at: http://creativecommons.org/licenses/by-nc/3.0/