Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis
KAUST DepartmentKAUST Catalysis Center (KCC)
Chemical Science Program
Physical Science and Engineering (PSE) Division
KAUST Grant NumberURF/1/4384
Online Publication Date2021-12-06
Permanent link to this recordhttp://hdl.handle.net/10754/673992
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AbstractMetallaphoto-catalysis has been established as a robust platform for efficient construction of a range of chemical bonds. Moreover, transformation of native functionalities such as C(sp3)–H bonds to produce functional molecules represents one of the most attractive strategies in organic synthesis. Merging two powerful methodologies, metallaphoto-catalyzed benzylic and allylic C(sp3)–H bond functionalizations provide a series of general and mild approaches for diversification of alkylbenzenes and alkenes.
CitationYue, H., Zhu, C., Huang, L., Dewanji, A., & Rueping, M. (2022). Advances in allylic and benzylic C–H bond functionalization enabled by metallaphotoredox catalysis. Chemical Communications. doi:10.1039/d1cc06285a
SponsorsThis work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).
PublisherRoyal Society of Chemistry (RSC)