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    Metal-free C-Se cross-coupling enabled by photoinduced inter-molecular charge transfer

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    manuscript.pdf
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    Description:
    Accepted manuscript
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    Type
    Article
    Authors
    Zhu, Chen cc
    Zhumagazy, Serik cc
    Yue, Huifeng cc
    Rueping, Magnus cc
    KAUST Department
    KAUST Catalysis Center (KCC)
    Chemical Science
    Physical Science and Engineering (PSE) Division
    Chemical Science Program
    KAUST Grant Number
    URF/1/4384
    Date
    2022
    Online Publication Date
    2021
    Embargo End Date
    2022-12-12
    Permanent link to this record
    http://hdl.handle.net/10754/673976
    
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    Abstract
    Metal-free C-Se cross-couplings via the formation of electron-donor-acceptor (EDA) complexes have been developed. The visible-light induced reactions can be applied for the synthesis of a series of unsymmetrical diaryl selenides employing aryl bromides, aryl iodides as well as aryl chlorides under mild reaction conditions. The scale-up was readily achieved. UV-Vis spectroscopy measurements provide insight into the reaction mechanism.
    Citation
    Zhu, C., Zhumagazy, S., Yue, H., & Rueping, M. (2022). Metal-free C–Se cross-coupling enabled by photoinduced inter-molecular charge transfer. Chemical Communications. doi:10.1039/d1cc06152f
    Sponsors
    This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4384).
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    CHEMICAL COMMUNICATIONS
    DOI
    10.1039/d1cc06152f
    Additional Links
    http://xlink.rsc.org/?DOI=D1CC06152F
    ae974a485f413a2113503eed53cd6c53
    10.1039/d1cc06152f
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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