• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguideTheses and Dissertations LibguideSubmit an Item

    Statistics

    Display statistics

    Y6 Organic Thin-Film Transistors with Electron Mobilities of 2.4 cm 2 V −1 s −1 via Microstructural Tuning

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    advs.202104977.pdf
    Size:
    1.955Mb
    Format:
    PDF
    Description:
    Publisher's Version/PDF
    Download
    Type
    Article
    Authors
    Gutierrez-Fernandez, Edgar
    Scaccabarozzi, Alberto D. cc
    Basu, Aniruddha cc
    Solano, Eduardo
    Anthopoulos, Thomas D. cc
    Martin, Jaime cc
    KAUST Department
    KAUST Solar Center (KSC)
    Material Science and Engineering Program
    Physical Science and Engineering (PSE) Division
    Date
    2021-12-02
    Permanent link to this record
    http://hdl.handle.net/10754/673942
    
    Metadata
    Show full item record
    Abstract
    There is a growing demand to attain organic materials with high electron mobility, μe , as current reliable reported values are significantly lower than those exhibited by their hole mobility counterparts. Here, it is shown that a well-known nonfullerene-acceptor commonly used in organic solar cells, that is, BTP-4F (aka Y6), enables solution-processed organic thin-film transistors (OTFT) with a μe as high as 2.4 cm2  V-1  s-1 . This value is comparable to those of state-of-the-art n-type OTFTs, opening up a plethora of new possibilities for this class of materials in the field of organic electronics. Such efficient charge transport is linked to a readily achievable highly ordered crystalline phase, whose peculiar structural properties are thoroughly discussed. This work proves that structurally ordered nonfullerene acceptors can exhibit intrinsically high mobility and introduces a new approach in the quest of high μe organic materials, as well as new guidelines for future materials design.
    Citation
    Gutierrez-Fernandez, E., Scaccabarozzi, A. D., Basu, A., Solano, E., Anthopoulos, T. D., & Martín, J. (2021). Y6 Organic Thin-Film Transistors with Electron Mobilities of 2.4 cm 2 V −1 s −1 via Microstructural Tuning. Advanced Science, 2104977. doi:10.1002/advs.202104977
    Sponsors
    J.M. thanks MICINN/FEDER for the Ramón y Cajal contract and the grant Ref. PGC2018-094620-A-I00). The Xunta de Galicia is also acknowledged for the grant Proyectos de Consolidación Ref. ED431F 2021/009. J.M and E.G.-F. acknowledge support through the European Union's Horizon 2020 research and innovation program, H2020-FETOPEN-01-2018-2020 (FET-Open Challenging Current Thinking), “LION-HEARTED′, grant agreement no. 828984. J.M would like to thank the financial support provided by the IONBIKE RISE project. This project has received funding from the European Union's Horizon 2020 research and innovation programme under the Marie Skłodowska-Curie grant agreement No 823989. The authors also thank the technical and human support provided by SGIker of UPV/EHU and the European funding (ERDF and ESF).
    Publisher
    Wiley
    Journal
    Advanced Science
    DOI
    10.1002/advs.202104977
    PubMed ID
    34854574
    Additional Links
    https://onlinelibrary.wiley.com/doi/10.1002/advs.202104977
    ae974a485f413a2113503eed53cd6c53
    10.1002/advs.202104977
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Material Science and Engineering Program; KAUST Solar Center (KSC)

    entitlement

    Related articles

    • Electron Mobility Exceeding 10 cm(2) V(-1) s(-1) and Band-Like Charge Transport in Solution-Processed n-Channel Organic Thin-Film Transistors.
    • Authors: Xu X, Yao Y, Shan B, Gu X, Liu D, Liu J, Xu J, Zhao N, Hu W, Miao Q
    • Issue date: 2016 Jul
    • Dual Imide-Functionalized Unit-Based Regioregular D-A<sub>1</sub>-D-A<sub>2</sub> Polymers for Efficient Unipolar n-Channel Organic Transistors and All-Polymer Solar Cells.
    • Authors: Wang Y, Kim SW, Lee J, Matsumoto H, Kim BJ, Michinobu T
    • Issue date: 2019 Jun 26
    • Critical role of alkyl chain branching of organic semiconductors in enabling solution-processed N-channel organic thin-film transistors with mobility of up to 3.50 cm² V(-1) s(-1).
    • Authors: Zhang F, Hu Y, Schuettfort T, Di CA, Gao X, McNeill CR, Thomsen L, Mannsfeld SC, Yuan W, Sirringhaus H, Zhu D
    • Issue date: 2013 Feb 13
    • n-Channel semiconductor materials design for organic complementary circuits.
    • Authors: Usta H, Facchetti A, Marks TJ
    • Issue date: 2011 Jul 19
    • Cyano-Substituted Head-to-Head Polythiophenes: Enabling High-Performance n-Type Organic Thin-Film Transistors.
    • Authors: Wang H, Huang J, Uddin MA, Liu B, Chen P, Shi S, Tang Y, Xing G, Zhang S, Woo HY, Guo H, Guo X
    • Issue date: 2019 Mar 13
    DSpace software copyright © 2002-2022  DuraSpace
    Quick Guide | Contact Us | KAUST University Library
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.