Perovskite-Nanosheet Sensitizer for Highly Efficient Organic X-ray Imaging Scintillator
Gutierrez Arzaluz, Luis
Mohammed, Omar F.
KAUST DepartmentAdvanced Membranes and Porous Materials Center, Division of Physical Science and Engineering, King Abdullah University of Science and Technology, Thuwal 23955-6900, Kingdom of Saudi Arabia
Advanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Functional Nanomaterials Lab (FuNL)
KAUST Catalysis Center (KCC)
KAUST Solar Center (KSC)
Material Science and Engineering Program
Nanostructured Functional Materials (NFM) laboratory
Physical Science and Engineering (PSE) Division
Ultrafast Laser Spectroscopy and Four-dimensional Electron Imaging Research Group
Embargo End Date2022-11-27
Permanent link to this recordhttp://hdl.handle.net/10754/673784
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AbstractThe weak X-ray capture capability of organic scintillators always leads to poor imaging resolution and detection sensitivity. Here, we realize an efficient and reabsorption-free organic scintillator at the interface of perovskite nanosheets using a very efficient energy transfer strategy. Our steady-state and ultrafast time-resolved experiments supported by density functional theory calculations demonstrate that an efficient interfacial energy transfer from the perovskite nanosheet to the organic chromophore with thermally activated delayed fluorescence (TADF) character can be achieved. Interestingly, we found that the direct harnessing of both singlet and triplet excitons of the TADF chromophores also contributed greatly to its remarkably enhanced radioluminescence intensity and X-ray sensitivity. A high X-ray imaging resolution of 135 μm and a low detection limit of 38.7 nGy/s were achieved in the fabricated X-ray imaging scintillator.
CitationWang, J.-X., Wang, X., Yin, J., Gutiérrez-Arzaluz, L., He, T., Chen, C., … Mohammed, O. F. (2021). Perovskite-Nanosheet Sensitizer for Highly Efficient Organic X-ray Imaging Scintillator. ACS Energy Letters, 10–16. doi:10.1021/acsenergylett.1c02173
SponsorsThis work was supported by King Abdullah University of Science and Technology (KAUST).
PublisherAmerican Chemical Society (ACS)
JournalACS Energy Letters