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dc.contributor.authorMuralirajan, Krishnamoorthy
dc.contributor.authorKancherla, Rajesh
dc.contributor.authorBau, Jeremy
dc.contributor.authorTaksande, Mayur Rahul
dc.contributor.authorQureshi, Muhammad
dc.contributor.authorTakanabe, Kazuhiro
dc.contributor.authorRueping, Magnus
dc.date.accessioned2021-11-25T08:07:57Z
dc.date.available2021-11-25T08:07:57Z
dc.date.issued2021-11-24
dc.date.submitted2021-09-05
dc.identifier.citationMuralirajan, K., Kancherla, R., Bau, J. A., Taksande, M. R., Qureshi, M., Takanabe, K., & Rueping, M. (2021). Exploring the Structure and Performance of Cd–Chalcogenide Photocatalysts in Selective Trifluoromethylation. ACS Catalysis, 14772–14780. doi:10.1021/acscatal.1c04053
dc.identifier.issn2155-5435
dc.identifier.issn2155-5435
dc.identifier.doi10.1021/acscatal.1c04053
dc.identifier.urihttp://hdl.handle.net/10754/673772
dc.description.abstractThe field of heterogeneous photoredox catalysis has grown substantially and impacted organic synthesis because of the affordability and reusability of catalysts. This study reports radical trifluoromethylation with Cd–chalcogenide semiconductors. Cd semiconductors, particularly CdSe, are readily available, commercial, visible-light-responsive, heterogeneous photocatalysts. The potential of readily available Cd semiconductors, particularly CdSe, is confirmed by their increased photocatalytic activity toward trifluoromethylation with various substrates, such as (hetero)arenes and vinylic amides/acids, via addition, cyclization, and decarboxylation under visible light. The economic significance of this strategy is also highlighted through the scalable synthesis of biologically active molecules followed by catalyst reuse. Moreover, these catalysts are relatively inexpensive compared with transition metal-based homogeneous photocatalysts, presently used in organic synthesis.
dc.description.sponsorshipThis work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4025).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acscatal.1c04053
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in ACS Catalysis, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acscatal.1c04053.
dc.titleExploring the Structure and Performance of Cd–Chalcogenide Photocatalysts in Selective Trifluoromethylation
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentChemical Science Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalACS Catalysis
dc.rights.embargodate2022-11-24
dc.eprint.versionPost-print
dc.contributor.institutionSLAC National Accelerator Laboratory, Stanford Synchrotron Radiation Lightsource, 2575 Sand Hill Road, Menlo Park, California 94025, United States
dc.contributor.institutionDepartment of Chemical System Engineering, School of Engineering, The University of Tokyo, 7-3-1 Hongo, Bunkyo-ku, Tokyo 113-8656, Japan
dc.identifier.pages14772-14780
kaust.personMuralirajan, Krishnamoorthy
kaust.personKancherla, Rajesh
kaust.personBau, Jeremy
kaust.personTaksande, Mayur Rahul
kaust.personQureshi, Muhammad
kaust.personRueping, Magnus
kaust.grant.numberURF/1/4025
dc.date.accepted2021-11-09
refterms.dateFOA2021-11-28T05:47:22Z
kaust.acknowledged.supportUnitOffice of Sponsored Research


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