Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes
KAUST Grant NumberCRG-1-2012-LAI-009
Permanent link to this recordhttp://hdl.handle.net/10754/672995
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AbstractAbstract Two hybrid materials composed of metal-organic framework (JUC-32) nanoparticles and carboxyl-modified multi-wall carbon nanotubes (MWCNTs) were synthesised successfully in situ and characterized by TEM, PXRD, and TGA. The gas adsorption properties of these two hybrid materials were compared with the original JUC-32 material and a physical mixture of JUC-32 and MWCNTs. The results indicated that the composite materials absorbed larger amounts of CO<inf>2</inf> and CH<inf>4</inf> per specific surface area than the original materials, and that the adsorption enthalpies of CO<inf>2</inf> and CH<inf>4</inf> had significantly increased.
CitationKang, Z., Xue, M., Zhang, D., Fan, L., Pan, Y., & Qiu, S. (2015). Hybrid metal-organic framework nanomaterials with enhanced carbon dioxide and methane adsorption enthalpy by incorporation of carbon nanotubes. Inorganic Chemistry Communications, 58, 79–83. doi:10.1016/j.inoche.2015.06.007
SponsorsThis work was supported by the National Natural Science Foundation of China (21390394), the National Basic Research Program of China (2012CB821700), NSFC (21261130584, 21201076, 21101072), 111 project (B07016), and Award Project of KAUST (CRG-1-2012-LAI-009).
PublisherELSEVIER SCIENCE BV