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Efficient and chemoselective hydrogenation of aldehydes catalyzed by a well-defined PN3 -pincer manganese (II) catalyst precursor: an application in furfural conversion

dc.contributor.authorHuang, Kuo-Wei
dc.contributor.authorGholap, Sandeep S.
dc.contributor.authorAl Dakhil, Abdullah
dc.contributor.authorChakraborty, Priyanka
dc.contributor.authorLi, Huaifeng
dc.contributor.authorDutta, Indranil
dc.contributor.authorDas, Pradip
dc.date.accessioned2021-10-19T06:55:41Z
dc.date.available2021-10-19T06:55:41Z
dc.date.issued2021
dc.date.submitted2021-08-28
dc.identifier.citationHuang, K.-W., Gholap, S. S., Al-Dakhil, A., Chakraborty, P., Li, H., Dutta, I., & Das, P. (2021). Efficient and chemoselective hydrogenation of aldehydes catalyzed by a well-defined PN3 -pincer manganese (II) catalyst precursor: an application in furfural conversion. Chemical Communications. doi:10.1039/d1cc04808b
dc.identifier.issn1359-7345
dc.identifier.issn1364-548X
dc.identifier.doi10.1039/d1cc04808b
dc.identifier.urihttp://hdl.handle.net/10754/672890
dc.description.abstractWell-defined and air-stable PN3-pincer manganese (II) complexes were synthesized and used for the hydrogenation of aldehydes into alcohols under mild conditions using MeOH as a solvent. This protocol is applicable for a wide range of aldehydes containing various functional groups. Importantly, α,β-unsaturated aldehydes, including ynals, are hydrogenated with the C=C double bond/CΞC triple bond intact. Our methodology was demonstrated for biomass derived feedstock such as furfural and 2,5-diformyl furfural to furfuryl alcohol and 2-hydroxy furfuryl alcohol respectively.
dc.description.sponsorshipThis work was supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://pubs.rsc.org/en/Content/ArticleLanding/2021/CC/D1CC04808B
dc.rightsThis article is licensed under a Creative Commons Attribution-NonCommercial 3.0 Unported Licence.
dc.rights.urihttp://creativecommons.org/licenses/by-nc/3.0/
dc.titleEfficient and chemoselective hydrogenation of aldehydes catalyzed by a well-defined PN3 -pincer manganese (II) catalyst precursor: an application in furfural conversion
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentHomogeneous Catalysis Laboratory (HCL)
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChemical Communications
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, College of Science, Imam Mohammad Ibn Saud Islamic University, Riyadh 11432-5701, Saudi Arabia.
kaust.personHuang, Kuo-Wei
kaust.personGholap, Sandeep S.
kaust.personAl Dakhil, Abdullah
kaust.personChakraborty, Priyanka
kaust.personLi, Huaifeng
kaust.personDutta, Indranil
kaust.personDas, Pradip
dc.date.accepted2021-10-14
refterms.dateFOA2021-10-19T06:56:51Z


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