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dc.contributor.authorWang, Yingge
dc.contributor.authorGhanem, Bader
dc.contributor.authorAli, Zain
dc.contributor.authorHazazi, Khalid
dc.contributor.authorHan, Yu
dc.contributor.authorPinnau, Ingo
dc.date.accessioned2021-09-15T06:47:29Z
dc.date.available2021-09-15T06:47:29Z
dc.date.issued2021-09-14
dc.date.submitted2021-04-17
dc.identifier.citationWang, Y., Ghanem, B. S., Ali, Z., Hazazi, K., Han, Y., & Pinnau, I. (2021). Recent Progress on Polymers of Intrinsic Microporosity and Thermally Modified Analogue Materials for Membrane-Based Fluid Separations. Small Structures, 2(9), 2170026. doi:10.1002/sstr.202170026
dc.identifier.issn2688-4062
dc.identifier.issn2688-4062
dc.identifier.doi10.1002/sstr.202170026
dc.identifier.urihttp://hdl.handle.net/10754/671227
dc.description.abstractSolution-processable amorphous glassy polymers of intrinsic microporosity (PIMs) are promising microporous organic materials for membrane-based gas and liquid separations due to their high surface area and internal free volume, thermal and chemical stability, and excellent separation performance. This review provides an overview of the most recent developments in the design and transport properties of novel ladder PIM materials, polyimides of intrinsic microporosity (PIM–PIs), functionalized PIMs and PIM–PIs, PIM-derived thermally rearranged (TR), and carbon molecular sieve (CMS) membrane materials as well as PIM-based thin film composite membranes for a wide range of energy-intensive gas and liquid separations. In less than two decades, PIMs have significantly lifted the performance upper bounds in H2/N2, H2/CH4, O2/N2, CO2/N2, and CO2/CH4 separations. However, PIMs are still limited by their insufficient gas-pair selectivity to be considered as promising materials for challenging industrial separations such as olefin/paraffin separations. An optimum pore size distribution is required to further improve the selectivity of a PIM for a given application. Specific attention is given to the potential use of PIM-based CMS membranes for energy-intensive CO2/CH4, N2/CH4, C2H4/C2H6, and C3H6/C3H8 separations, and thin film composite membranes containing PIM motifs for liquid separations.
dc.description.sponsorshipKing Abdullah University of Science and Technology. Grant Numbers: BAS/1/1323-01-01, BAS/1/1372-01-01.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/sstr.202170026
dc.rightsArchived with thanks to Small Structures
dc.titleRecent Progress on Polymers of Intrinsic Microporosity and Thermally Modified Analogue Materials for Membrane-Based Fluid Separations
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentChemical Science Program
dc.identifier.journalSmall Structures
dc.rights.embargodate2022-09-14
dc.eprint.versionPost-print
dc.identifier.volume2
dc.identifier.issue9
dc.identifier.pages2170026
kaust.personWang, Yingge
kaust.personGhanem, Bader
kaust.personAli, Zain
kaust.personHazazi, Khalid
kaust.personHan, Yu
kaust.personPinnau, Ingo
kaust.grant.numberBAS/1/1323-01-01
kaust.grant.numberBAS/1/1372-01-01.
dc.date.accepted2021-07-06
refterms.dateFOA2021-09-16T05:46:14Z


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