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dc.contributor.authorWu, Melissa M.
dc.contributor.authorGill, Arran M.
dc.contributor.authorLu Yunpeng
dc.contributor.authorFalivene, Laura
dc.contributor.authorLi Yongxin
dc.contributor.authorGanguly, Rakesh
dc.contributor.authorCavallo, Luigi
dc.contributor.authorGarcia, Felipe
dc.date.accessioned2021-07-05T08:54:17Z
dc.date.available2021-07-05T08:54:17Z
dc.date.issued2015-02-13
dc.date.submitted2015-01-08
dc.identifier.citationWu. M, M., Gill, A. M., Yunpeng, L., Falivene, L., Yongxin, L., Ganguly, R., … García, F. (2015). Synthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes. Dalton Transactions, 44(34), 15166–15174. doi:10.1039/c5dt00079c
dc.identifier.issn1477-9234
dc.identifier.issn1477-9226
dc.identifier.doi10.1039/c5dt00079c
dc.identifier.urihttp://hdl.handle.net/10754/670013
dc.description.abstractTreatment of a series of aromatic NHCs (IMes, SIMes, IPr and SIPr) with trimethylaluminium produced their corresponding Lewis acid–base adducts: IMes·AlMe3 (1), SIMes·AlMe3 (2), IPr·AlMe3 (3), and SIPr·AlMe3 (4). These complexes expand the few known examples of saturated NHC stabilised Group 13 complexes. Furthermore, compounds 1–4 show differential stability depending on the nature of the NHC ligand. Analyses of topographic steric maps and NHC %VBur were used to explain these differences. All the compounds have been fully characterised by multinuclear NMR spectroscopy, IR and single crystal X-ray analysis together with computational studies.
dc.publisherRoyal Society of Chemistry (RSC)
dc.relation.urlhttp://xlink.rsc.org/?DOI=C5DT00079C
dc.rightsThis article is licensed under a Creative Commons Attribution 3.0 Unported Licence.
dc.rights.urihttp://creativecommons.org/licenses/by/3.0/
dc.titleSynthesis, structural studies and ligand influence on the stability of aryl-NHC stabilised trimethylaluminium complexes
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentChemical Science Program
dc.identifier.journalDALTON TRANSACTIONS
dc.identifier.wosutWOS:000359952000018
dc.eprint.versionPost-print
dc.contributor.institutionSchool of Physical and Mathematical Sciences
dc.contributor.institutionDivision of Chemistry and Biological Chemistry
dc.contributor.institutionNanyang Technological University
dc.contributor.institutionSingapore 637371
dc.contributor.institutionChemistry
dc.contributor.institutionFaculty of Natural and Environmental Sciences
dc.contributor.institutionUniversity of Southampton
dc.contributor.institutionHighfield Southampton
dc.contributor.institutionUK
dc.contributor.institutionSaudi Arabia
dc.contributor.institutionDipartimento di chimica
dc.contributor.institutionUniverità di Salerno
dc.identifier.volume44
dc.identifier.issue34
dc.identifier.pages15166-15174
kaust.personFalivene, Laura
kaust.personFalivene, Laura
kaust.personCavallo, Luigi
kaust.personCavallo, Luigi
dc.date.accepted2015-02-13
dc.identifier.eid2-s2.0-84939806680
refterms.dateFOA2021-07-05T08:56:07Z


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