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dc.contributor.authorShao, Ping
dc.contributor.authorZhou, Wei
dc.contributor.authorHong, Qin-Long
dc.contributor.authorYi, Luocai
dc.contributor.authorZheng, Lirong
dc.contributor.authorWang, Wenjing
dc.contributor.authorZhang, Hai-Xia
dc.contributor.authorZhang, Huabin
dc.contributor.authorZhang, Jian
dc.date.accessioned2021-06-09T06:24:13Z
dc.date.available2021-06-09T06:24:13Z
dc.date.issued2021-05-12
dc.identifier.citationShao, P., Zhou, W., Hong, Q.-L., Yi, L., Zheng, L., Wang, W., … Zhang, J. (2021). Synthesis of Boron-imidazolate Framework nanosheet with Dimer Cu units for CO2 Electroreduction to Ethylene. Angewandte Chemie International Edition. doi:10.1002/anie.202106004
dc.identifier.issn1433-7851
dc.identifier.pmid33978299
dc.identifier.doi10.1002/anie.202106004
dc.identifier.urihttp://hdl.handle.net/10754/669466
dc.description.abstractFundamental understanding of the dependence between the structure and composition on the electrochemical CO 2 reduction reaction (CO 2 RR) would guide the rational design of highly efficient and selective electrocatalysts. A major impediment to the deep reduction CO 2 to multi-carbon products is the complexity of carbon-carbon bond coupling. The chemically well-defined catalysts with atomically dispersed dual-metal sites are required for these C-C coupling involved processes. Here, we developed a catalyst (BIF-102NSs) that features Cl - bridged dimer copper (Cu 2 ) units, which delivers high catalytic activity and selectivity for C 2 H 4 . Mechanistic investigation verifies that neighboring Cu monomers not only perform as regulator for varying the reaction barrier, but also afford distinct reaction paths compared with isolated monomers, resulting in greatly improved electroreduction performance for CO 2 .
dc.description.sponsorshipThis work is supported by National Natural Science Foundation of China (21935010, 21773242), National Key Research and Development Program of China (2018YFA0208600), and the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB20000000).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202106004
dc.rightsArchived with thanks to Angewandte Chemie (International ed. in English)
dc.subjectCO2 reduction
dc.subjectelectrocatalysis
dc.subjectcrystal
dc.subjectmetal-organic framework
dc.subjectcatalyst
dc.titleSynthesis of Boron-imidazolate Framework nanosheet with Dimer Cu units for CO2 Electroreduction to Ethylene.
dc.typeArticle
dc.contributor.departmentKing Abdullah University of Science and Technology chemistry SAUDI ARABIA
dc.identifier.journalAngewandte Chemie (International ed. in English)
dc.rights.embargodate2022-05-12
dc.eprint.versionPost-print
dc.contributor.institutionChinese Academy of Sciences Fujian Institute of Research on the Structure of Matter chemistry CHINA
dc.contributor.institutionTianjin University physical CHINA
dc.contributor.institutionChinese Academy of Sciences physical CHINA
dc.contributor.institutionFujian Institute of Research on the Structure of Matter Chemistry 155 Yangqiao west road 350002 Fuzhou CHINA
kaust.personZhang, Huabin
refterms.dateFOA2021-06-09T08:34:00Z


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