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dc.contributor.authorNolan, Steven Patrick
dc.contributor.authorTzouras, Nikolaos V.
dc.contributor.authorMartynova, Ekaterina A.
dc.contributor.authorMa, Xinyuan
dc.contributor.authorScattolin, Thomas
dc.contributor.authorHupp, Benjamin
dc.contributor.authorBusen, Hendrik
dc.contributor.authorSaab, Marina
dc.contributor.authorZhang, Ziyun
dc.contributor.authorFalivene, Laura
dc.contributor.authorPisanò, Gianmarco
dc.contributor.authorVan Hecke, Kristof
dc.contributor.authorCavallo, Luigi
dc.contributor.authorCazin, Catherine S. J.
dc.contributor.authorSteffen, Andreas
dc.date.accessioned2021-05-27T12:05:28Z
dc.date.available2021-05-27T12:05:28Z
dc.date.issued2021-05-26
dc.date.submitted2021-04-25
dc.identifier.citationNolan, S. P., Tzouras, N. V., Martynova, E. A., Ma, X., Scattolin, T., Hupp, B., … Steffen, A. (2021). Simple Synthetic Routes to Carbene-M-Amido (M = Cu, Ag, Au) Complexes for Luminescence and Photocatalysis Applications. Chemistry – A European Journal. doi:10.1002/chem.202101476
dc.identifier.issn0947-6539
dc.identifier.issn1521-3765
dc.identifier.doi10.1002/chem.202101476
dc.identifier.urihttp://hdl.handle.net/10754/669279
dc.description.abstractThe development of novel and operationally simple synthetic routes to Carbene-Metal-Amido (CMA) complexes of copper, silver and gold relevant for photonic applications are reported. A mild base and sustainable solvents allow all operations to be conducted in air and at room temperature, leading to high yields of the targeted compounds even on multigram scales. The effect of various mild bases on the N-H metallation was studied in silico and experimentally, while a mechanochemical, solvent-free synthetic approach was also developed. Our photophysical studies on [M(NHC)(Cbz)] indicate that the occurrence of fluorescent or phosphorescent states is determined primarily by the metal, providing control over the excited state properties. Consequently, we demonstrate the potential of the new CMAs beyond luminescence applications by employing a selected CMA as a photocatalyst. The exemplified synthetic ease is expected to accelerate the applications of CMAs in photocatalysis and materials chemistry.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/chem.202101476
dc.rightsArchived with thanks to Chemistry – A European Journal
dc.titleSimple Synthetic Routes to Carbene-M-Amido (M = Cu, Ag, Au) Complexes for Luminescence and Photocatalysis Applications
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.identifier.journalChemistry – A European Journal
dc.rights.embargodate2022-05-26
dc.eprint.versionPost-print
dc.contributor.institutionUniversiteit Gent Chemistry Krijgslaan 281-S3 9000 Ghent BELGIUM
dc.contributor.institutionGhent University: Universiteit Gent Chemistry BELGIUM
dc.contributor.institutionTU Dortmund University: Technische Universitat Dortmund Chemistry GERMANY
dc.contributor.institutionTU Dortmund: Technische Universitat Dortmund Chemistry GERMANY
dc.contributor.institutionUGent: Universiteit Gent Chemistry BELGIUM
kaust.personZhang, Ziyun
kaust.personFalivene, Laura
kaust.personCavallo, Luigi
dc.date.accepted2021-05-26
refterms.dateFOA2021-05-27T12:07:53Z


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