Synthesis and characterization of second-generation phosphorus-nitrogen PN 3 P-rhodium (I) pincer complexes via ligand post-modification
KAUST DepartmentChemical Science Program
Physical Science and Engineering (PSE) Division
KAUST Catalysis Center (KCC)
KAUST Catalysis Center and Division of Physical Science and Engineering, King Abdullah University of Science and Technology Thuwal 23955-6900 Saudi Arabia.
Online Publication Date2021-05-07
Print Publication Date2021-07-27
Embargo End Date2022-05-07
Permanent link to this recordhttp://hdl.handle.net/10754/669163
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AbstractA pseudo-dearomatized PN3P*Rh−CO complex reacts with various alkyl/benzyl halides to furnish a series of second-generation PN3P-pincer carbonyl complexes via the ligand post-modification strategy. These synthesized complexes were fully characterized by NMR, FTIR, HRMS, and single-crystal X-ray crystallography. A plausible mechanism for the formation of 2nd-generation PN3P complexes was proposed based on the isolation of the minor dialkylated products.
CitationZhou, C., Hu, J., Chakraborty, P., & Huang, K. (2021). Synthesis and characterization of second-generation phosphorus-nitrogen PN 3 P-rhodium (I) pincer complexes via ligand post-modification. Zeitschrift Für Anorganische Und Allgemeine Chemie. doi:10.1002/zaac.202100050
SponsorsWe acknowledge the financial support from King AbdullahUniversity of Science and Technology (KAUST).