Implications of co-feeding water on the growth mechanisms of retained species on a SAPO-18 catalyst during the methanol-to-olefins reaction
KAUST DepartmentKing Abdullah University of Science and Technology KAUST Catalysis Center King Abdullah University of Science and TechnologyArabia Saudí 23955-6900 Thuwal SAUDI ARABIA
Physical Science and Engineering (PSE) Division
Online Publication Date2021-05-18
Print Publication Date2021-07-07
Embargo End Date2022-04-19
Permanent link to this recordhttp://hdl.handle.net/10754/668968
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AbstractThe dynamics of retained and deactivating species in a SAPO-18 catalyst during the methanol-to-olefins reaction have been followed using a combination of ex-situ and in-situ techniques; performed in differential and integral reactors. The retained species have been analyzed using extraction, in-situ FTIR and in-situ UV-vis spectroscopies combined with online product analysis (gas chromatography and mass spectrometry). In particular, here we provide the detailed composition of the retained species given by the high-resolution mass spectrometry (LDI FT-ICR MS). We observe a decrease of both formation and degradation rates of retained species by water, whereas the extent of these decreases is the same across the entire spectrum of retained molecules. This result is profound because it indicates that added water unselectively quenches the formation of active and deactivating species. At the same time, the catalyst can have an extended lifetime by adding water and we proved that this is due to the expulsion of species (particularly olefins) out of the SAPO-18 framework, and subsequent growth of heavy polycyclic aromatic structures that imply less deactivation. These conclusions can be extrapolated to other MTO catalysts with relatively similar pore topology such as SAPO-34 or SSZ-13 structures.
CitationValecillos, J., Hita, I., Sastre, E., Aguayo, A. T., & Castaño, P. (2021). Implications of co-feeding water on the growth mechanisms of retained species on a SAPO-18 catalyst during the methanol-to-olefins reaction. ChemCatChem. doi:10.1002/cctc.202100124
SponsorsThis work was possible thanks to the financial support of the Ministry of Economy, Industry and Competitiveness of the Spanish Government (Project CTQ2016-79646-P, co-founded with ERDF funds), the Basque Government (Project IT748-13, IT912-16) and the King Abdullah University of Science and Technology (KAUST). J.V. is thankful for his fellowship granted by the Ministry of Economy, Industry and Competitiveness of the Spanish Government (BES-2014-069980). The authors are thankful for technical and human support provided by IZO-SGI SGIker of UPV/EHU and European funding (ERDF and ESF).