Dopant-Assisted Matrix Stabilization Enables Thermoelectric Performance Enhancement in n-Type Quantum Dot Films.
AuthorsNugraha, Mohamad Insan
El Labban, Abdulrahman
García de Arquer, F Pelayo
Alshareef, Husam N.
KAUST DepartmentPhysical Science and Engineering Division (PSE), KAUST Solar Center (KSC), King Abdullah University of Science and Technology (KAUST), Thuwal 23955-6900, Saudi Arabia
Material Science and Engineering Program
Physical Science and Engineering (PSE) Division
KAUST Solar Center (KSC)
KAUST Grant NumberCRG2018-3737.
Embargo End Date2022-04-15
Permanent link to this recordhttp://hdl.handle.net/10754/668824
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AbstractEfficient thermoelectric generators require further progress in developing n-type semiconductors that combine low thermal conductivity with high electrical conductivity. By embedding colloidal quantum dots (CQDs) in a metal halide matrix (QDMH), the metal halide matrix can enhance phonon scattering, thus suppressing thermal transport; however, simultaneously achieving high electrical conductivity in such systems has previously been limited by the deleterious impact of a large density of interfaces on charge transport. Therefore, new strategies are needed to improve charge carrier transport without sacrificing matrix-enabled low thermal transport. Here, we report the use of chemical doping in the solution state to improve electron transport while maintaining low thermal transport in QDMH films. By incorporating cesium carbonate (Cs2CO3) salts as a dopant prior to matrix formation, we find that the dopant stabilizes the matrix in colloidal inks and enables efficient n-type doping in QDMH films. As a result, this strategy leads to an enhanced n-type thermoelectric behavior in solution-processed QDMH films near room temperature, with a thermal conductivity of 0.25 W m–1 K–1—significantly lower than in prior films based on organic-ligand-cross-linked CQD films (>0.6 W m–1 K–1) and spark-plasma-sintered CQD systems (>1 W m–1 K–1). This study provides a pathway to developing efficient n-type thermoelectric materials with low thermal conductivity using single-step deposition and low-temperature processing.
CitationNugraha, M. I., Sun, B., Kim, H., El-Labban, A., Desai, S., Chaturvedi, N., … Baran, D. (2021). Dopant-Assisted Matrix Stabilization Enables Thermoelectric Performance Enhancement in n-Type Quantum Dot Films. ACS Applied Materials & Interfaces. doi:10.1021/acsami.1c01886
SponsorsThe authors would like to acknowledge Nimer Wehbe at KAUST Core Labs for supporting XPS measurements in this work. Research in this publication was supported by the King Abdullah University of Science and Technology (KAUST) Office of Sponsored Research (OSR) under Award no. OSRCRG2018-3737.
PublisherAmerican Chemical Society (ACS)
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