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dc.contributor.authorHeister, Katja
dc.contributor.authorLima, Ana Teresa
dc.date.accessioned2021-04-12T13:10:31Z
dc.date.available2021-04-12T13:10:31Z
dc.date.issued2019-09-09
dc.identifier.citationHeister, K., & Lima, A. T. (2019). Soil heterogeneity and surfactant desorption influence PAH distribution during electroremediation at a tar oil–contaminated site. Environmental Monitoring and Assessment, 191(10). doi:10.1007/s10661-019-7776-6
dc.identifier.issn0167-6369
dc.identifier.issn1573-2959
dc.identifier.doi10.1007/s10661-019-7776-6
dc.identifier.urihttp://hdl.handle.net/10754/668702
dc.description.abstractAfter a field experiment utilising electroosmosis and non-ionic surfactant Tween 80 as a remediation effort on the removal of polycyclic aromatic hydrocarbons (PAHs) from a long-term asphalt-contaminated soil, the PAH heterogeneity in the soil was yet extensive. This study come as a follow-up to address the following questions: (i) was PAH (re)distribution a consequence of the treatment? and (ii) to what extent does the surfactant affected PAH desorption and subsequent bioavailability? To answer question (i), we selected random soil samples from different locations of the field site before in situ remediation took place, and quantified and characterised soil organic matter by elemental analysis and solid-phase 13C nuclear magnetic resonance spectroscopy and PAH concentrations. Finally, batch desorption experiments with selected contaminated soil samples were carried out with and without 1% Tween 80 in the solution phase to address question (ii). Data shows that PAH concentrations were related neither to organic matter content nor to a high aromaticity of the organic matter, which serves as a proxy for the presence of tar oil. Soil heterogeneity is likely to be the cause of PAH heterogeneous distribution, but it is inferred that remediation causes weathering of the tar oil phase, resulting in the release and subsequent transport and sorption of PAH to inherent organic material. The results of the batch desorption experiments demonstrate PAH desorption up to 146 times when surfactant is present. However, Tween 80 does not enable biodegradation, since desorbed PAH molecules are entrapped inside surfactant micelles.
dc.description.sponsorshipWe are grateful to Bärbel Deischl and Uta Lindstedt (Technische Universität München) for the PAH analysis and conduction of the desorption experiment, respectively. In addition, we thank Frank Volkering (Tauw B.V.) for providing the sample material and information about the field site.
dc.description.sponsorshipThis study was financially supported by the King Abdullah University of Science and Technology (KAUST) in the framework of the SOWACOR Centre in Development at Utrecht University (grant no. KUK-C1-017-12).
dc.publisherSpringer Nature
dc.relation.urlhttp://link.springer.com/10.1007/s10661-019-7776-6
dc.rightsArchived with thanks to Environmental Monitoring and Assessment
dc.titleSoil heterogeneity and surfactant desorption influence PAH distribution during electroremediation at a tar oil–contaminated site
dc.typeArticle
dc.identifier.journalEnvironmental Monitoring and Assessment
dc.eprint.versionPost-print
dc.contributor.institutionLehrstuhl für Bodenkunde, Technische Universität München, 85350, Freising-Weihenstephan, Germany
dc.contributor.institutionGeoLab, Faculty of Geosciences, Utrecht University, Princetonlaan 8, 3584, CB, Utrecht, The Netherlands
dc.contributor.institutionDepartment of Environmental Engineering, Universidade Federal do Espírito Santo, Av. Fernando Ferrari, 514, Goiabeiras, Vitoria, 29075-910, Brazil
dc.contributor.institutionDepartment of Earth and Environmental Sciences, 200 University Avenue West, Waterloo, Ontario, N2L 3G1, Canada
dc.identifier.volume191
dc.identifier.issue10
kaust.grant.numberKUK-C1-017-12
dc.identifier.eid2-s2.0-85071991406


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