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dc.contributor.authorTian, Hao
dc.contributor.authorHuang, Fei
dc.contributor.authorZhu, Yihan
dc.contributor.authorLiu, Shaomin
dc.contributor.authorHan, Yu
dc.contributor.authorJaroniec, Mietek
dc.contributor.authorYang, Qihua
dc.contributor.authorLiu, Hongyang
dc.contributor.authorLu, Gao Qing Max
dc.contributor.authorLiu, Jian
dc.date.accessioned2021-04-12T06:27:00Z
dc.date.available2021-04-12T06:27:00Z
dc.date.issued2018-08-06
dc.identifier.citationTian, H., Huang, F., Zhu, Y., Liu, S., Han, Y., Jaroniec, M., … Liu, J. (2018). Submicroreactors: The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability (Adv. Funct. Mater. 32/2018). Advanced Functional Materials, 28(32), 1870227. doi:10.1002/adfm.201870227
dc.identifier.issn1616-301X
dc.identifier.doi10.1002/adfm.201870227
dc.identifier.urihttp://hdl.handle.net/10754/668667
dc.description.abstractDesign of multicomponent yolk–shell structures is crucial for the fabrication of micro/nanoreactors for a variety of applications. This work reports the rational design and synthesis of yolk–shell-structured submi-croreactors with loaded metal nanoparticles into ZnO–microporous carbon core–shell structures. The solvothermal treatment and carbonization pro-cess of uniform zeolitic imidazolate framework-8 (ZIF-8)@resin polymer core–shell structures leads to the generation of yolk–shell-structured ZnO@carbon. The synthesis conditions are optimized to track the evolu-tion of ZIF-8 in a confined space of resin polymer as a submicroreactor itself. It is found that nanoribbon evolution occurs via the formation of the intermediate needle-like particles. The Pd&ZnO@carbon submicro-reactor is shown to be a highly selective catalyst (selectivity >99%) for hydrogenation of phenylacetylene to phenylethylene. The excellent perfor-mance of Pd&ZnO@carbon particles is evidenced by higher conversion and selectivity than that of Pd/ZnO and Pd/C with similar Pd loading. Furthermore, Pd&ZnO@carbon submicroreactors show superior catalytic stability, and no deactivation after 25 h of reaction. The proposed strategy is promising for the design of multifunctional micro/nanoreactors or nano-containers for construction of artificial cells.
dc.publisherWiley
dc.relation.urlhttp://doi.wiley.com/10.1002/adfm.201870227
dc.rightsArchived with thanks to Advanced Functional Materials
dc.titleSubmicroreactors: The Development of Yolk-Shell-Structured Pd&ZnO@Carbon Submicroreactors with High Selectivity and Stability (Adv. Funct. Mater. 32/2018)
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentNanostructured Functional Materials (NFM) laboratory
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAdvanced Functional Materials
dc.eprint.versionPost-print
dc.contributor.institutionState Key Laboratory of Catalysis; iChEM; Dalian Institute of Chemical Physics; Chinese Academy of Sciences; 457 Zhongshan Road Dalian 116023 China
dc.contributor.institutionDepartment of Chemical Engineering; Curtin University; Perth WA 6845 Australia
dc.contributor.institutionShenyang National Laboratory for Materials Science; Institute of Metal Research; Chinese Academy of Sciences; 72 Wenhua Road Shenyang 110016 China
dc.contributor.institutionDepartment of Chemical Engineering; Zhejiang University of Technology; Hangzhou 310014 China
dc.contributor.institutionDepartment of Chemistry and Biochemistry; Kent State University; Kent OH 44242 USA
dc.contributor.institutionVice-Chancellor's Office; University of Surrey; Guildford Surrey GU2 7XH UK
dc.contributor.institutionDepartment of Chemical and Process Engineering; University of Surrey; Guildford Surrey GU2 7XH UK
dc.identifier.volume28
dc.identifier.issue32
dc.identifier.pages1870227
kaust.personZhu, Yihan
kaust.personHan, Yu


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