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dc.contributor.authorZubar, Viktoriia
dc.contributor.authorDewanji, Abhishek
dc.contributor.authorRueping, Magnus
dc.date.accessioned2021-03-24T06:39:18Z
dc.date.available2021-03-24T06:39:18Z
dc.date.issued2021-03-23
dc.date.submitted2021-02-24
dc.identifier.citationZubar, V., Dewanji, A., & Rueping, M. (2021). Chemoselective Hydrogenation of Nitroarenes Using an Air-Stable Base-Metal Catalyst. Organic Letters. doi:10.1021/acs.orglett.1c00659
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.doi10.1021/acs.orglett.1c00659
dc.identifier.urihttp://hdl.handle.net/10754/668219
dc.description.abstractThe reduction of nitroarenes to anilines as well as azobenzenes to hydrazobenzenes using a single base-metal catalyst is reported. The hydrogenation reactions are performed with an air-and moisture-stable manganese catalyst and proceed under relatively mild reaction conditions. The transformation tolerates a broad range of functional groups, affording aniline derivatives and hydrazobenzenes in high yields. Mechanistic studies suggest that the reaction proceeds via a bifunctional activation involving metal–ligand cooperative catalysis.
dc.description.sponsorshipWe thank Dr. Jan Sklyaruk for his support in preparing the revision.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.orglett.1c00659
dc.rights.urihttps://creativecommons.org/licenses/by/4.0/
dc.titleChemoselective Hydrogenation of Nitroarenes Using an Air-Stable Base-Metal Catalyst
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganic Letters
dc.eprint.versionPublisher's Version/PDF
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany
kaust.personRueping, Magnus
refterms.dateFOA2021-03-24T06:40:06Z


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