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dc.contributor.authorChen, Qiang
dc.contributor.authorXian, Shikai
dc.contributor.authorDong, Xinglong
dc.contributor.authorLiu, Yanyao
dc.contributor.authorWang, Hao
dc.contributor.authorOlson, David H.
dc.contributor.authorWilliams, Lawrence J.
dc.contributor.authorHan, Yu
dc.contributor.authorBu, Xian-He
dc.contributor.authorLi, Jing
dc.date.accessioned2021-03-16T06:48:16Z
dc.date.available2021-03-16T06:48:16Z
dc.date.issued2021-03-11
dc.identifier.citationChen, Q., Xian, S., Dong, X., Liu, Y., Wang, H., Olson, D. H., … Li, J. (2021). High-Efficiency Separation of n-Hexane by A Dynamic Metal-Organic Framework with Reduced Energy Consumption. Angewandte Chemie International Edition. doi:10.1002/anie.202100707
dc.identifier.issn1433-7851
dc.identifier.issn1521-3773
dc.identifier.pmid33704894
dc.identifier.doi10.1002/ange.202100707
dc.identifier.doi10.1002/anie.202100707
dc.identifier.urihttp://hdl.handle.net/10754/668110
dc.description.abstractThe separation of n -alkanes from their branched isomers is vitally important to improve octane rating of gasoline. To facilitate mass transfer, adsorptive separation is usually operated under high temperatures in industry, which require considerable energy. Herein, we present a kind of dynamic pillar-layered MOF that exhibits self-adjustable structure and pore space, a behavior induced by guest molecules. A combination of the flexibility of the framework with the commensurate adsorption for n -Hexane results in exceptional performance in separating hexane isomers. More significantly, lower temperature prompts the guest molecules to open the dynamic pores, which may provide a new perspective for optimized separation performance at lower temperatures with less energy consumption.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202100707
dc.rightsArchived with thanks to Angewandte Chemie International Edition
dc.subjectdynamic framework
dc.subjectbreathing effect
dc.subjecthydrocarbon separation
dc.subjectenergy consumption reduction
dc.titleHigh-Efficiency Separation of n-Hexane by A Dynamic Metal-Organic Framework with Reduced Energy Consumption
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentBiological and Environmental Sciences and Engineering (BESE) Division
dc.contributor.departmentChemical Science Program
dc.contributor.departmentNanostructured Functional Materials (NFM) laboratory
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie International Edition
dc.rights.embargodate2022-03-11
dc.eprint.versionPost-print
dc.contributor.institutionSchool of Materials Science and Engineering, National Institute for Advanced Materials, Nankai University, Tianjin 300350, China
dc.contributor.institutionDepartment of Chemistry and Chemical Biology, Rutgers University, 610 Taylor Road, Piscataway, NJ 08854, USA
dc.contributor.institutionBeijing Key Laboratory for Green Catalysis and Separation, College of Environmental and Energy Engineering, Beijing University of Technology, Beijing 100124, China
dc.contributor.institutionHoffmann Institute of Advanced Materials, Shenzhen Polytechnic, 7098 Liuxian Boulevard, Shenzhen, Guangdong 518055, China
dc.contributor.institutionState Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China
kaust.personDong, Xinglong
kaust.personHan, Yu
refterms.dateFOA2021-03-16T06:48:39Z


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