Tungsten Blue Oxide as a Reusable Electrocatalyst for Acidic Water Oxidation by Plasma-Induced Vacancy Engineering
Emwas, Abdul-Hamid M.
Alshareef, Husam N.
KAUST DepartmentPhysical Science and Engineering (PSE) Division
KAUST Catalysis Center (KCC)
Material Science and Engineering Program
Chemical Science Program
Biological and Environmental Sciences and Engineering (BESE) Division
Permanent link to this recordhttp://hdl.handle.net/10754/667283
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AbstractIn contrast to alkaline water electrolysis, acidic water electrolysis remains an elusive goal due to the lack of earth-abundant, efficient, and acid-stable water oxidation electrocatalysts. Here, we show that materials with intrinsically poor electrocatalytic activity can be turned into active electrocatalysts that drive the acidic oxygen evolution reaction (OER) effectively. This development is achieved through ultrafast plasma sputtering, which introduces abundant oxygen vacancies that reconstruct the surface electronic structures, and thus, regulated the surface interactions of electrocatalysts and the OER intermediates. Using tungsten oxide (WO3) as an example, we present a broad spectrum of theoretical and experimental characterizations that show an improved energetics of OER originating from surface oxygen vacancies and resulting in a significantly boosted OER performance, compared with pristine WO3. Our result suggests the efficacy of using defect chemistry to modify electronic properties and hence to improve the OER performance of known materials with poor activity, providing a new direction for the discovery of acid-stable OER catalysts.
CitationLiang, H., Cao, Z., Xia, C., Ming, F., Zhang, W., Emwas, A.-H., … Alshareef, H. N. (2020). Tungsten Blue Oxide as a Reusable Electrocatalyst for Acidic Water Oxidation by Plasma-Induced Vacancy Engineering. CCS Chemistry, 1553–1561. doi:10.31635/ccschem.020.202000325
PublisherChinese Chemical Society