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dc.contributor.authorOsipova, K.N.
dc.contributor.authorSarathy, Mani
dc.contributor.authorKorobeinichev, Oleg P.
dc.contributor.authorShmakov, A.G.
dc.date.accessioned2021-01-07T12:06:11Z
dc.date.available2021-01-07T12:06:11Z
dc.date.issued2021-01-05
dc.date.submitted2020-11-12
dc.identifier.citationOsipova, K. N., Sarathy, S. M., Korobeinichev, O. P., & Shmakov, A. G. (2021). Laminar Burning Velocities of Formic Acid and Formic Acid/Hydrogen Flames: An Experimental and Modeling Study. Energy & Fuels. doi:10.1021/acs.energyfuels.0c03818
dc.identifier.issn0887-0624
dc.identifier.issn1520-5029
dc.identifier.doi10.1021/acs.energyfuels.0c03818
dc.identifier.urihttp://hdl.handle.net/10754/666840
dc.description.abstractLaminar flame speed of formic acid and formic acid/hydrogen (4/1) flames was studied both experimentally and numerically. Experiments with flames of pure formic acid were performed at temperatures of 373 and 423 K, while for formic acid/hydrogen flames the temperature value was 368 K. All of the experiments were performed under atmospheric pressure and at an equivalence ratio ranging from 0.5 to 1.5. To measure the laminar flame speed, the heat flux balance technique was applied. Three detailed chemical-kinetic mechanisms were tested on experimental data. Experiments showed that addition of 20% of hydrogen increases the laminar burning velocity of formic acid, for example, at around 1.5 for stoichiometric flames. The comparison of experimental and numerical data showed that all models tend to overestimate laminar burning velocities of studied flames, especially in the case of rich flames. The obtained results indicate that further improvement of existing chemical-kinetic models of formic acid oxidation is highly required.
dc.description.sponsorshipThe reported study was funded by RFBR under project No.20-33-90163. The research at King Abdullah University of Science and Technology (KAUST) was supported by Saudi Aramco.
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.energyfuels.0c03818
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Energy & Fuels, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.energyfuels.0c03818.
dc.titleLaminar Burning Velocities of Formic Acid and Formic Acid/Hydrogen Flames: An Experimental and Modeling Study
dc.typeArticle
dc.contributor.departmentChemical Engineering Program
dc.contributor.departmentClean Combustion Research Center
dc.contributor.departmentCombustion and Pyrolysis Chemistry (CPC) Group
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalEnergy & Fuels
dc.rights.embargodate2022-01-05
dc.eprint.versionPost-print
dc.contributor.institutionVoevodsky Institute of Chemical Kinetics and Combustion SB RAS, Novosibirsk 630090, Russia
dc.contributor.institutionNovosibirsk State University, Novosibirsk 630090, Russia
kaust.personSarathy, Mani
dc.date.accepted2020-12-20
refterms.dateFOA2021-01-10T06:29:03Z
dc.date.published-online2021-01-05
dc.date.published-print2021-01-21


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