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dc.contributor.authorLiu, D.
dc.contributor.authorKHALED, Fethi
dc.contributor.authorFarooq, Aamir
dc.date.accessioned2020-12-30T12:27:14Z
dc.date.available2020-12-30T12:27:14Z
dc.date.issued2017-01-01
dc.identifier.urihttp://hdl.handle.net/10754/666771
dc.description.abstract-Valerolactone (GVL) is a promising bio-based platform molecule. Hydrogen (H) abstraction is the main consumption pathway for GVL at intermediate to high temperature conditions. Overall reaction rate coefficients are measured in a shock tube for the reaction of GVL with hydroxyl radicals over 990 – 1294 K and pressures near 1.2 atm. Ultraviolet OH absorption diagnostic is used to measure the consumption of OH radicals. This work presents the first direct measurements of the titled reaction. Results are fitted in Arrhenius expression: = 4.87 × 10−10(−4440 /) 3−1−1 The data from this work are compared with GVL isomer and show reasonable agreement with the experimental values of methyl butanoate.
dc.publisherCombustion Institute
dc.relation.urlhttps://research.kaust.edu.sa/en/publications/high-temperature-rate-constant-measurement-for-the-reaction-of-gv
dc.rightsArchived with thanks to Combustion Institute
dc.titleHigh-temperature rate constant measurement for the reaction of GVL with OH
dc.typeConference Paper
dc.contributor.departmentClean Combustion Research Center, Physical Science and Engineering Division, King Abdullah University of Science and Technology, Thuwal, 23955-6900, Saudi Arabia
dc.contributor.departmentMechanical Engineering Program
dc.contributor.departmentMechanical Engineering
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentClean Combustion Research Center
dc.conference.date2017-12-10 to 2017-12-14
dc.conference.name11th Asia-Pacific Conference on Combustion, ASPACC 2017
dc.conference.locationSydney, NSW, AUS
dc.eprint.versionPre-print
dc.identifier.volume2017-December
kaust.personLiu, D.
kaust.personKhaled, Fathi
kaust.personFarooq, Aamir
dc.identifier.eid2-s2.0-85046396633


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