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On the N-Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes**

dc.contributor.authorKadari, Lingaswamy
dc.contributor.authorErb, William
dc.contributor.authorHalauko, Yury S.
dc.contributor.authorIvashkevich, Oleg A.
dc.contributor.authorMatulis, Vadim E.
dc.contributor.authorLyakhov, Dmitry
dc.contributor.authorRoisnel, Thierry
dc.contributor.authorRadha Krishna, Palakodety
dc.contributor.authorMongin, Florence
dc.date.accessioned2020-12-27T08:25:07Z
dc.date.available2020-12-27T08:25:07Z
dc.date.issued2020-12-22
dc.date.submitted2020-09-28
dc.identifier.citationKadari, L., Erb, W., Halauko, Y. S., Ivashkevich, O. A., Matulis, V. E., Lyakhov, D., … Mongin, F. (2020). On the N -Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes**. European Journal of Inorganic Chemistry. doi:10.1002/ejic.202000904
dc.identifier.issn1099-0682
dc.identifier.issn1434-1948
dc.identifier.doi10.1002/ejic.202000904
dc.identifier.urihttp://hdl.handle.net/10754/666657
dc.description.abstractVarious 2-, 3- and 1’-substituted iodoferrocenes were reacted with acetamide in the presence of copper(I) iodide (1 equiv), N,N’-dimethylethylenediamine (1 equiv), tripotassium phosphate (2 equiv) in dioxane at 90 °C for 14 h, and allowed a large range of original 1,2-, 1,3- and 1,1’-disubstituted ferrocenes to be obtained. The results were compared as a function of the substituent and its position on the ring. DFT calculations revealed higher activation barrier for the oxidative addition in the ferrocene series when compared with classical planar aromatics. Structure-property relationships were applied to rationalize the reactivity of the different iodoferrocenes.
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/ejic.202000904
dc.rightsArchived with thanks to European Journal of Inorganic Chemistry
dc.titleOn the N-Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes**
dc.typeArticle
dc.contributor.departmentVisual Computing Center (VCC)
dc.contributor.departmentComputer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
dc.identifier.journalEuropean Journal of Inorganic Chemistry
dc.rights.embargodate2021-12-22
dc.eprint.versionPost-print
dc.contributor.institutionUniv Rennes, CNRS, ISCR (Institut des Sciences Chimiques de Rennes)-UMR 6226, 35000, Rennes, France
dc.contributor.institutionOrganic Synthesis and Process Chemistry Division, CSIR-Indian Institute of Chemical Technology, Hyderabad, 500007, India
dc.contributor.institutionUNESCO Chair of Belarusian State University, 14 Leningradskaya Str., Minsk, 220030, Belarus
dc.contributor.institutionResearch Institute for Physico-Chemical Problems of Belarusian State University, 14 Leningradskaya Str., Minsk, 220030, Belarus
kaust.personLyakhov, Dmitry
dc.date.accepted2020-11-06
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s12
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s23
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s34
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s45
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s78
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s67
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc260s56
dc.identifier.eid2-s2.0-85097885674
refterms.dateFOA2021-01-04T06:42:37Z
display.relations<b>Is Supplemented By:</b><br/> <ul><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026533: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S12. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s12" >10.5517/ccdc.csd.cc260s12</a> Handle: <a href="http://hdl.handle.net/10754/674292" >10754/674292</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026534: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S23. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s23" >10.5517/ccdc.csd.cc260s23</a> Handle: <a href="http://hdl.handle.net/10754/674294" >10754/674294</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026535: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S34. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s34" >10.5517/ccdc.csd.cc260s34</a> Handle: <a href="http://hdl.handle.net/10754/674295" >10754/674295</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026536: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S45. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s45" >10.5517/ccdc.csd.cc260s45</a> Handle: <a href="http://hdl.handle.net/10754/674296" >10754/674296</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026539: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S78. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s78" >10.5517/ccdc.csd.cc260s78</a> Handle: <a href="http://hdl.handle.net/10754/674297" >10754/674297</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). CCDC 2026538: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S67. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s67" >10.5517/ccdc.csd.cc260s67</a> Handle: <a href="http://hdl.handle.net/10754/674298" >10754/674298</a></a></li><li><i>[Dataset]</i> <br/> Kadari, Lingaswamy, Erb, William, Halauko, Yury S., Ivashkevich, Oleg A., Matulis, Vadim E., Lyakhov, Dmitry, Roisnel, Thierry, Krishna, Palakodety Radha, &amp; Mongin, Florence. (2021). <i>CCDC 2026537: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC260S56. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc260s56" >10.5517/ccdc.csd.cc260s56</a> Handle: <a href="http://hdl.handle.net/10754/687104" >10754/687104</a></a></li></ul>
dc.date.published-online2020-12-22
dc.date.published-print2021-01-26


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