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    On the N-Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes**

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    Name:
    Main amidation FcI Erb EJIC_new-HAL.pdf
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    796.9Kb
    Format:
    PDF
    Description:
    Accepted manuscript
    Embargo End Date:
    2021-12-22
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    Type
    Article
    Authors
    Kadari, Lingaswamy
    Erb, William cc
    Halauko, Yury S.
    Ivashkevich, Oleg A.
    Matulis, Vadim E.
    Lyakhov, Dmitry cc
    Roisnel, Thierry
    Radha Krishna, Palakodety
    Mongin, Florence
    KAUST Department
    Visual Computing Center (VCC)
    Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division
    Date
    2020-12-22
    Embargo End Date
    2021-12-22
    Submitted Date
    2020-09-28
    Permanent link to this record
    http://hdl.handle.net/10754/666657
    
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    Abstract
    Various 2-, 3- and 1’-substituted iodoferrocenes were reacted with acetamide in the presence of copper(I) iodide (1 equiv), N,N’-dimethylethylenediamine (1 equiv), tripotassium phosphate (2 equiv) in dioxane at 90 °C for 14 h, and allowed a large range of original 1,2-, 1,3- and 1,1’-disubstituted ferrocenes to be obtained. The results were compared as a function of the substituent and its position on the ring. DFT calculations revealed higher activation barrier for the oxidative addition in the ferrocene series when compared with classical planar aromatics. Structure-property relationships were applied to rationalize the reactivity of the different iodoferrocenes.
    Citation
    Kadari, L., Erb, W., Halauko, Y. S., Ivashkevich, O. A., Matulis, V. E., Lyakhov, D., … Mongin, F. (2020). On the N -Arylation of Acetamide Using 2-, 3- and 1’-Substituted Iodoferrocenes**. European Journal of Inorganic Chemistry. doi:10.1002/ejic.202000904
    Publisher
    Wiley
    Journal
    European Journal of Inorganic Chemistry
    DOI
    10.1002/ejic.202000904
    Additional Links
    https://onlinelibrary.wiley.com/doi/10.1002/ejic.202000904
    ae974a485f413a2113503eed53cd6c53
    10.1002/ejic.202000904
    Scopus Count
    Collections
    Articles; Visual Computing Center (VCC); Computer, Electrical and Mathematical Sciences and Engineering (CEMSE) Division

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