Highly sensitive non-enzymatic detection of glucose at mwcnt-cubtc composite electrode
Szerb, Elisabeta I.
KAUST DepartmentPhysical Science and Engineering (PSE) Division
Chemical Engineering Program
KAUST Catalysis Center (KCC)
Permanent link to this recordhttp://hdl.handle.net/10754/666249
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AbstractA novel electrochemical glucose sensor was developed, based on a multiwall carbon nanotubes (MWCNTs)-copper-1,3,5-benzenetricarboxylic acid (CuBTC)-epoxy composite electrode, named MWCNT-CuBTC. The electrode nanocomposite was prepared by a two-roll mill procedure and characterized morphostructurally by scanning electron microscopy (SEM). The CuBTC formed defined crystals with a wide size distribution, which were well dispersed and embedded in the MWCNTs. Its electrical conductivity was determined by four-point probe contact (DC) conductivity measurements. The electroactive surface area, determined using cyclic voltammetry (CV), was found to be 6.9 times higher than the geometrical one. The results of the electrochemical measurements using CV, linear sweep voltammetry (LSV), differential pulse voltammetry (DPV), chronoamperometry (CA) and multiple pulse amperometry (MPA) showed that the MWCNT-CuBTC composite electrode displayed high electrocatalytic activity toward the oxidation of glucose and, as a consequence, very high sensitivity. The best sensitivity of 14,949 µAmM−1cm−1 was reached using MPA at the potential value of 0.6 V/SCE, which was much higher in comparison with other copper-based electrodes reported in the literature. The good analytical performance, low cost and simple preparation method make this novel electrode material promising for the development of an effective glucose sensor.
CitationRemes, A., Manea, F., Motoc (m. Ilies), S., Baciu, A., Szerb, E. I., Gascon, J., & Gug, G. (2020). Highly Sensitive Non-Enzymatic Detection of Glucose at MWCNT-CuBTC Composite Electrode. Applied Sciences, 10(23), 8419. doi:10.3390/app10238419
Sponsorsfor this study was provided by a grant from the Romanian Ministry of Research and Innovation, project number PN-III-P1-1.2-PCCDI-2017-0245/26 PCCDI/2018 (SUSTENVPRO), within PNCDI III, and by a grant from the Romanian Ministry of Education and Research, CNCS—UEFISCDI, project number PD 88/2020, project code PN-III-P1-1.1-PD-2019-0676, within PNCDI III. Conflicts of Interest: The authors declare no conflict of interest.
JournalApplied Sciences (Switzerland)
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