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dc.contributor.authorZhu, Chen
dc.contributor.authorYue, Huifeng
dc.contributor.authorJia, Jiaqi
dc.contributor.authorRueping, Magnus
dc.date.accessioned2020-12-02T08:23:43Z
dc.date.available2020-12-02T08:23:43Z
dc.date.issued2021-02-25
dc.date.submitted2020-10-14
dc.identifier.citationZhu, C., Yue, H., Jia, J., & Rueping, M. (2020). Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination. Angewandte Chemie International Edition. doi:10.1002/anie.202013852
dc.identifier.issn1433-7851
dc.identifier.pmid33252192
dc.identifier.doi10.1002/anie.202013852
dc.identifier.doi10.1002/ange.202013852
dc.identifier.urihttp://hdl.handle.net/10754/666223
dc.description.abstractThe formation of C-heteroatom bonds represents an important type of bond-forming reaction in organic synthesis and often provides a fast and efficient access to privileged structures found in pharmaceuticals, agrochemical and materials. In contrast to conventional Pd- or Cu-catalyzed C-heteroatom cross-couplings under high-temperature conditions, recent advances in homo- and heterogeneous Ni-catalyzed C-heteroatom formations under mild conditions are particularly attractive from the standpoint of sustainability and practicability. The generation of Ni III and excited Ni II intermediates facilitate the reductive elimination step to achieve mild cross-couplings. This minireview provides an overview of the state-of-the-art approaches for mild C-heteroatom bond formations highlights the developments in photoredox and nickel dual catalysis involving SET and energy transfer processes; photoexcited nickel cataylsis; electro and nickel dual catalysis; heterogeneous photoredox and nickel dual catalysis involving graphitic carbon nitride (mpg-CN), metal organic frameworks (MOFs) or semiconductor quantum dots (QDs); as well as more conventional zinc and nickel dual catalyzed reactions.
dc.description.sponsorshipThis work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4025).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/anie.202013852
dc.rightsArchived with thanks to Angewandte Chemie (International ed. in English)
dc.titleRecent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination.
dc.typeArticle
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentKing Abdullah University of Science and Technology KAUST Catalysis Center SAUDI ARABIA
dc.contributor.departmentChemical Science Program
dc.identifier.journalAngewandte Chemie (International ed. in English)
dc.rights.embargodate2021-11-30
dc.eprint.versionPost-print
kaust.personZhu, Chen
kaust.personYue, Huifeng
kaust.personJia, Jiaqi
kaust.personRueping, Magnus
kaust.grant.numberURF/1/4025
dc.date.accepted2020-11-23
refterms.dateFOA2020-12-02T08:27:08Z
kaust.acknowledged.supportUnitOffice of Sponsored Research
dc.date.published-online2021-02-25
dc.date.published-print2021-08-09


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