Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination.
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2021-11-30
Type
ArticleKAUST Department
KAUST Catalysis Center (KCC)Physical Science and Engineering (PSE) Division
King Abdullah University of Science and Technology KAUST Catalysis Center SAUDI ARABIA
Chemical Science Program
KAUST Grant Number
URF/1/4025Date
2020-11-30Embargo End Date
2021-11-30Submitted Date
2020-10-14Permanent link to this record
http://hdl.handle.net/10754/666223
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The formation of C-heteroatom bonds represents an important type of bond-forming reaction in organic synthesis and often provides a fast and efficient access to privileged structures found in pharmaceuticals, agrochemical and materials. In contrast to conventional Pd- or Cu-catalyzed C-heteroatom cross-couplings under high-temperature conditions, recent advances in homo- and heterogeneous Ni-catalyzed C-heteroatom formations under mild conditions are particularly attractive from the standpoint of sustainability and practicability. The generation of Ni III and excited Ni II intermediates facilitate the reductive elimination step to achieve mild cross-couplings. This minireview provides an overview of the state-of-the-art approaches for mild C-heteroatom bond formations highlights the developments in photoredox and nickel dual catalysis involving SET and energy transfer processes; photoexcited nickel cataylsis; electro and nickel dual catalysis; heterogeneous photoredox and nickel dual catalysis involving graphitic carbon nitride (mpg-CN), metal organic frameworks (MOFs) or semiconductor quantum dots (QDs); as well as more conventional zinc and nickel dual catalyzed reactions.Citation
Zhu, C., Yue, H., Jia, J., & Rueping, M. (2020). Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination. Angewandte Chemie International Edition. doi:10.1002/anie.202013852Sponsors
This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4025).Publisher
WileyPubMed ID
33252192Additional Links
https://onlinelibrary.wiley.com/doi/10.1002/anie.202013852ae974a485f413a2113503eed53cd6c53
10.1002/anie.202013852
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