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    Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination.

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    Recent Advances.pdf
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    3.025Mb
    Format:
    PDF
    Description:
    Accepted manuscript
    Embargo End Date:
    2021-11-30
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    Type
    Article
    Authors
    Zhu, Chen cc
    Yue, Huifeng
    Jia, Jiaqi
    Rueping, Magnus cc
    KAUST Department
    KAUST Catalysis Center (KCC)
    Physical Science and Engineering (PSE) Division
    King Abdullah University of Science and Technology KAUST Catalysis Center SAUDI ARABIA
    Chemical Science Program
    KAUST Grant Number
    URF/1/4025
    Date
    2020-11-30
    Embargo End Date
    2021-11-30
    Submitted Date
    2020-10-14
    Permanent link to this record
    http://hdl.handle.net/10754/666223
    
    Metadata
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    Abstract
    The formation of C-heteroatom bonds represents an important type of bond-forming reaction in organic synthesis and often provides a fast and efficient access to privileged structures found in pharmaceuticals, agrochemical and materials. In contrast to conventional Pd- or Cu-catalyzed C-heteroatom cross-couplings under high-temperature conditions, recent advances in homo- and heterogeneous Ni-catalyzed C-heteroatom formations under mild conditions are particularly attractive from the standpoint of sustainability and practicability. The generation of Ni III and excited Ni II intermediates facilitate the reductive elimination step to achieve mild cross-couplings. This minireview provides an overview of the state-of-the-art approaches for mild C-heteroatom bond formations highlights the developments in photoredox and nickel dual catalysis involving SET and energy transfer processes; photoexcited nickel cataylsis; electro and nickel dual catalysis; heterogeneous photoredox and nickel dual catalysis involving graphitic carbon nitride (mpg-CN), metal organic frameworks (MOFs) or semiconductor quantum dots (QDs); as well as more conventional zinc and nickel dual catalyzed reactions.
    Citation
    Zhu, C., Yue, H., Jia, J., & Rueping, M. (2020). Recent Advances in Nickel-Catalyzed C-Heteroatom Cross-Coupling Reactions under Mild Conditions via Facilitated Reductive Elimination. Angewandte Chemie International Edition. doi:10.1002/anie.202013852
    Sponsors
    This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (URF/1/4025).
    Publisher
    Wiley
    Journal
    Angewandte Chemie (International ed. in English)
    DOI
    10.1002/anie.202013852
    10.1002/ange.202013852
    PubMed ID
    33252192
    Additional Links
    https://onlinelibrary.wiley.com/doi/10.1002/anie.202013852
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.202013852
    Scopus Count
    Collections
    Articles; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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