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dc.contributor.authorAlsadun, Norah Sadun
dc.contributor.authorMouchaham, Georges
dc.contributor.authorGuillerm, Vincent
dc.contributor.authorCzaban-Jozwiak, Justyna
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorJiang, Hao
dc.contributor.authorBhatt, Prashant
dc.contributor.authorParvatkar, Prakash Tukaram
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2020-11-22T13:39:36Z
dc.date.available2020-11-22T13:39:36Z
dc.date.issued2020-11-19
dc.date.submitted2020-09-18
dc.identifier.citationAlsadun, N., Mouchaham, G., Guillerm, V., Czaban-Jóźwiak, J., Shkurenko, A., Jiang, H., … Eddaoudi, M. (2020). Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study. Journal of the American Chemical Society. doi:10.1021/jacs.0c10007
dc.identifier.issn0002-7863
dc.identifier.issn1520-5126
dc.identifier.pmid33211955
dc.identifier.doi10.1021/jacs.0c10007
dc.identifier.urihttp://hdl.handle.net/10754/666070
dc.description.abstractHerein we report novel mesoporous zirconium-based metal-organic frameworks (MOFs) with zeolitic sodalite (sod) topology. Zr-sod-ZMOF-1 and -2 are constructed based on a novel cantellation design strategy. Distinctly, organic linkers are judiciously designed in order to promote the deployment of the 12-coordinated Zr hexanuclear molecular building block (MBB) as a tetrahedral secondary building unit, a prerequisite for zeolite-like nets. The resultant Zr-sod-ZMOFs exhibit mesopores with a diameter up to ≈43 Å, while the pore volume of 1.98 cm3·g-1 measured for Zr-sod-ZMOF-1 is the highest reported experimental value for zeolite-like MOFs based on MBBs as tetrahedral nodes.
dc.description.sponsorshipResearch reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/jacs.0c10007
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Journal of the American Chemical Society, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/jacs.0c10007.
dc.titleIntroducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentChemical Science
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.identifier.journalJournal of the American Chemical Society
dc.rights.embargodate2021-11-19
dc.eprint.versionPost-print
dc.contributor.institutionDepartment of Chemistry, College of Science, King Faisal University (KFU), Al-Ahsa 31982-400, Saudi Arabia
kaust.personAlsadun, Norah Sadun
kaust.personMouchaham, Georges
kaust.personGuillerm, Vincent
kaust.personCzaban-Jozwiak, Justyna
kaust.personShkurenko, Aleksander
kaust.personJiang, Hao
kaust.personBhatt, Prashant
kaust.personParvatkar, Prakash Tukaram
kaust.personEddaoudi, Mohamed
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc25hn4h
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc25hn2f
dc.relation.issupplementedbyDOI:10.5517/ccdc.csd.cc25hn3g
refterms.dateFOA2020-11-23T06:32:28Z
display.relations<b>Is Supplemented By:</b><br/> <ul><li><i>[Dataset]</i> <br/> Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, &amp; Eddaoudi, Mohamed. (2020). <i>CCDC 2011036: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN4H. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc25hn4h" >10.5517/ccdc.csd.cc25hn4h</a> Handle: <a href="http://hdl.handle.net/10754/667643" >10754/667643</a></a></li><li><i>[Dataset]</i> <br/> Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, &amp; Eddaoudi, Mohamed. (2020). <i>CCDC 2011034: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN2F. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc25hn2f" >10.5517/ccdc.csd.cc25hn2f</a> Handle: <a href="http://hdl.handle.net/10754/667647" >10754/667647</a></a></li><li><i>[Dataset]</i> <br/> Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, &amp; Eddaoudi, Mohamed. (2020). <i>CCDC 2011035: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN3G. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc25hn3g" >10.5517/ccdc.csd.cc25hn3g</a> Handle: <a href="http://hdl.handle.net/10754/667648" >10754/667648</a></a></li></ul>


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