Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study

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Type
Article
Authors
Alsadun, Norah Sadun cc
Mouchaham, Georges cc
Guillerm, Vincent cc
Czaban-Jozwiak, Justyna
Shkurenko, Aleksander cc
Jiang, Hao cc
Bhatt, Prashant
Parvatkar, Prakash Tukaram cc
Eddaoudi, Mohamed cc
KAUST Department
Chemical Science Program
Chemical Science
Physical Science and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Date
2020-11-19
Embargo End Date
2021-11-19
Submitted Date
2020-09-18
Permanent link to this record
http://hdl.handle.net/10754/666070

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Abstract
Herein we report novel mesoporous zirconium-based metal-organic frameworks (MOFs) with zeolitic sodalite (sod) topology. Zr-sod-ZMOF-1 and -2 are constructed based on a novel cantellation design strategy. Distinctly, organic linkers are judiciously designed in order to promote the deployment of the 12-coordinated Zr hexanuclear molecular building block (MBB) as a tetrahedral secondary building unit, a prerequisite for zeolite-like nets. The resultant Zr-sod-ZMOFs exhibit mesopores with a diameter up to ≈43 Å, while the pore volume of 1.98 cm3·g-1 measured for Zr-sod-ZMOF-1 is the highest reported experimental value for zeolite-like MOFs based on MBBs as tetrahedral nodes.
Citation
Alsadun, N., Mouchaham, G., Guillerm, V., Czaban-Jóźwiak, J., Shkurenko, A., Jiang, H., … Eddaoudi, M. (2020). Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study. Journal of the American Chemical Society. doi:10.1021/jacs.0c10007
Sponsors
Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
Publisher
American Chemical Society (ACS)
Journal
Journal of the American Chemical Society
DOI
10.1021/jacs.0c10007
PubMed ID
33211955
Additional Links
https://pubs.acs.org/doi/10.1021/jacs.0c10007
Relations
Is Supplemented By:
  • [Dataset]
    Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011036: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN4H. DOI: 10.5517/ccdc.csd.cc25hn4h Handle: 10754/667643
  • [Dataset]
    Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011034: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN2F. DOI: 10.5517/ccdc.csd.cc25hn2f Handle: 10754/667647
  • [Dataset]
    Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011035: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN3G. DOI: 10.5517/ccdc.csd.cc25hn3g Handle: 10754/667648
Collections
Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program