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    Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study

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    Type
    Article
    Authors
    Alsadun, Norah Sadun cc
    Mouchaham, Georges cc
    Guillerm, Vincent cc
    Czaban-Jozwiak, Justyna
    Shkurenko, Aleksander cc
    Jiang, Hao cc
    Bhatt, Prashant
    Parvatkar, Prakash Tukaram cc
    Eddaoudi, Mohamed cc
    KAUST Department
    Chemical Science Program
    Chemical Science
    Physical Science and Engineering (PSE) Division
    Advanced Membranes and Porous Materials Research Center
    Date
    2020-11-19
    Embargo End Date
    2021-11-19
    Submitted Date
    2020-09-18
    Permanent link to this record
    http://hdl.handle.net/10754/666070
    
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    Abstract
    Herein we report novel mesoporous zirconium-based metal-organic frameworks (MOFs) with zeolitic sodalite (sod) topology. Zr-sod-ZMOF-1 and -2 are constructed based on a novel cantellation design strategy. Distinctly, organic linkers are judiciously designed in order to promote the deployment of the 12-coordinated Zr hexanuclear molecular building block (MBB) as a tetrahedral secondary building unit, a prerequisite for zeolite-like nets. The resultant Zr-sod-ZMOFs exhibit mesopores with a diameter up to ≈43 Å, while the pore volume of 1.98 cm3·g-1 measured for Zr-sod-ZMOF-1 is the highest reported experimental value for zeolite-like MOFs based on MBBs as tetrahedral nodes.
    Citation
    Alsadun, N., Mouchaham, G., Guillerm, V., Czaban-Jóźwiak, J., Shkurenko, A., Jiang, H., … Eddaoudi, M. (2020). Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study. Journal of the American Chemical Society. doi:10.1021/jacs.0c10007
    Sponsors
    Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).
    Publisher
    American Chemical Society (ACS)
    Journal
    Journal of the American Chemical Society
    DOI
    10.1021/jacs.0c10007
    PubMed ID
    33211955
    Additional Links
    https://pubs.acs.org/doi/10.1021/jacs.0c10007
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    • [Dataset]
      Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011036: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN4H. DOI: 10.5517/ccdc.csd.cc25hn4h Handle: 10754/667643
    • [Dataset]
      Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011034: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN2F. DOI: 10.5517/ccdc.csd.cc25hn2f Handle: 10754/667647
    • [Dataset]
      Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011035: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN3G. DOI: 10.5517/ccdc.csd.cc25hn3g Handle: 10754/667648
    ae974a485f413a2113503eed53cd6c53
    10.1021/jacs.0c10007
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Chemical Science Program

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