Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study
Type
ArticleAuthors
Alsadun, Norah Sadun
Mouchaham, Georges

Guillerm, Vincent

Czaban-Jozwiak, Justyna
Shkurenko, Aleksander

Jiang, Hao

Bhatt, Prashant
Parvatkar, Prakash Tukaram

Eddaoudi, Mohamed

KAUST Department
Chemical Science ProgramChemical Science
Physical Science and Engineering (PSE) Division
Advanced Membranes and Porous Materials Research Center
Date
2020-11-19Embargo End Date
2021-11-19Submitted Date
2020-09-18Permanent link to this record
http://hdl.handle.net/10754/666070
Metadata
Show full item recordAbstract
Herein we report novel mesoporous zirconium-based metal-organic frameworks (MOFs) with zeolitic sodalite (sod) topology. Zr-sod-ZMOF-1 and -2 are constructed based on a novel cantellation design strategy. Distinctly, organic linkers are judiciously designed in order to promote the deployment of the 12-coordinated Zr hexanuclear molecular building block (MBB) as a tetrahedral secondary building unit, a prerequisite for zeolite-like nets. The resultant Zr-sod-ZMOFs exhibit mesopores with a diameter up to ≈43 Å, while the pore volume of 1.98 cm3·g-1 measured for Zr-sod-ZMOF-1 is the highest reported experimental value for zeolite-like MOFs based on MBBs as tetrahedral nodes.Citation
Alsadun, N., Mouchaham, G., Guillerm, V., Czaban-Jóźwiak, J., Shkurenko, A., Jiang, H., … Eddaoudi, M. (2020). Introducing a Cantellation Strategy for the Design of Mesoporous Zeolite-like Metal–Organic Frameworks: Zr-sod-ZMOFs as a Case Study. Journal of the American Chemical Society. doi:10.1021/jacs.0c10007Sponsors
Research reported in this publication was supported by the King Abdullah University of Science and Technology (KAUST).Publisher
American Chemical Society (ACS)PubMed ID
33211955Additional Links
https://pubs.acs.org/doi/10.1021/jacs.0c10007Relations
Is Supplemented By:- [Dataset]
Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011036: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN4H. DOI: 10.5517/ccdc.csd.cc25hn4h Handle: 10754/667643 - [Dataset]
Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011034: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN2F. DOI: 10.5517/ccdc.csd.cc25hn2f Handle: 10754/667647 - [Dataset]
Alsadun, Norah, Mouchaham, Georges, Guillerm, Vincent, Czaban-Jóźwiak, Justyna, Shkurenko, Aleksander, Jiang, Hao, Bhatt, Prashant M., Parvatkar, Prakash, & Eddaoudi, Mohamed. (2020). CCDC 2011035: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC25HN3G. DOI: 10.5517/ccdc.csd.cc25hn3g Handle: 10754/667648
ae974a485f413a2113503eed53cd6c53
10.1021/jacs.0c10007
Scopus Count
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