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dc.contributor.authorHadjichristidis, Nikos
dc.contributor.authorJiang, Yu
dc.date.accessioned2020-10-13T10:40:53Z
dc.date.available2020-10-13T10:40:53Z
dc.date.issued2020-11-19
dc.date.submitted2020-09-29
dc.identifier.citationHadjichristidis, N., & Jiang, Y. (2020). Diels-Alder Polymer Networks with Temperature-Reversible Cross-Linking-Induced Emission Yu Jiang*, and Nikos Hadjichristidis*. Angewandte Chemie. doi:10.1002/ange.202013183
dc.identifier.issn0044-8249
dc.identifier.issn1521-3757
dc.identifier.doi10.1002/ange.202013183
dc.identifier.doi10.1002/anie.202013183
dc.identifier.urihttp://hdl.handle.net/10754/665547
dc.description.abstractA novel synthetic strategy toward reversible cross-linked polymeric materials with tunable fluorescence properties is presented. Dimaleimide-substituted tetraphenylethene (TPE-2MI), which is nonemissive due to the photo-induced electron transfer (PET) between maleimide (MI) and tetraphenylethene (TPE) groups, was used to cross-link random copolymers of methyl (MM), decyl (DM) or lauryl (LM) with furfuryl methacrylate (FM). The mixture of copolymer and TPE-2MI in DMF showed reversible fluorescence with “on/off” behavior depending on the Diels-Alder (DA)/retro-DA process, which is easily adjusted by temperature. At high temperatures, the retro-DA reaction of polymer networks is dominant, and the fluorescence is quenched by the PET mechanism. In contrast, at low temperatures, the emission recovers as the DA reaction takes over. Based on these results, a transparent PMFM/TPE-2MI film was prepared, and the emission behavior was investigated. It was found that the polymer film shows an accurate response to the external temperature and exhibited tunable fluorescent “turn on/off” behavior. These excitingresults suggest the possible application of this type of reversible cross-linked materials in many areas, including information security and transmission. An example of invisible/visible writing is given.
dc.description.sponsorshipThe research reported in this publication was supported by King Abdullah University of Science and Technology (KAUST).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/10.1002/ange.202013183
dc.rightsArchived with thanks to Angewandte Chemie
dc.titleDiels-Alder Polymer Networks with Temperature-Reversible Cross-Linking-Induced Emission Yu Jiang*, and Nikos Hadjichristidis*
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.contributor.departmentPolymer Synthesis Laboratory
dc.identifier.journalAngewandte Chemie
dc.rights.embargodate2021-10-08
dc.eprint.versionPost-print
dc.contributor.institutionSouth-Central University for Nationalities College of Resources and Environmental Science CHINA
kaust.personHadjichristidis, Nikos
dc.date.accepted2020-10-05
refterms.dateFOA2020-10-13T10:44:06Z


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