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    Titanium methyl tamed on silica: synthesis of a well-defined pre-catalyst for hydrogenolysis of n-alkane

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    Name:
    CH-ChemComm proof (002).pdf
    Size:
    1.089Mb
    Format:
    PDF
    Description:
    Accepted manuscript
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    Type
    Article
    Authors
    Saidi, Aya cc
    Almaksoud, Walid
    Samantaray, Manoja K. cc
    Abou-Hamad, Edy cc
    Basset, Jean-Marie cc
    KAUST Department
    Chemical Science Program
    Chemical Science
    Physical Science and Engineering (PSE) Division
    KAUST Catalysis Center (KCC)
    Imaging and Characterization Core Lab
    NMR
    Date
    2020
    Embargo End Date
    2021-10-05
    Submitted Date
    2020-08-27
    Permanent link to this record
    http://hdl.handle.net/10754/665528
    
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    Abstract
    Alkylation of Ti(CH3)2Cl2 1 by MeLi gives the homoleptic Ti(CH3)42 for the first time in the absence of any coordinating solvent. The reaction of 2 with silica pretreated at 700 8C (SiO2–700) gives two inequivalent silica-supported Ti-methyl species 3. Complex 3 was characterized by IR, microanalysis (ICP-OES, CHNS, and gas quantification), and advanced solid-state NMR spectroscopy (1H, 13C, DQ, TQ, and HETCOR). The catalytic activity of the precatalyst 3 is investigated in low-temperature hydrogenolysis of propane and n-butane with TONs of 419 and 578, respectively
    Citation
    Saidi, A., Al Maksoud, W., Samantaray, M. K., Abou-Hamad, E., & Basset, J.-M. (2020). Titanium methyl tamed on silica: synthesis of a well-defined pre-catalyst for hydrogenolysis of n-alkane. Chemical Communications. doi:10.1039/d0cc05816e
    Publisher
    Royal Society of Chemistry (RSC)
    Journal
    Chemical Communications
    DOI
    10.1039/d0cc05816e
    Additional Links
    http://xlink.rsc.org/?DOI=D0CC05816E
    ae974a485f413a2113503eed53cd6c53
    10.1039/d0cc05816e
    Scopus Count
    Collections
    Articles; Imaging and Characterization Core Lab; Physical Science and Engineering (PSE) Division; Chemical Science Program; KAUST Catalysis Center (KCC)

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