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dc.contributor.authorLi, Jiantang
dc.contributor.authorKan, Liang
dc.contributor.authorLi, Jiyang
dc.contributor.authorLiu, Yunling
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2020-09-09T06:55:46Z
dc.date.available2020-09-09T06:55:46Z
dc.date.issued2020-08-26
dc.date.submitted2020-05-14
dc.identifier.citationLi, J., Kan, L., Li, J., Liu, Y., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal–Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie. doi:10.1002/ange.202006978
dc.identifier.issn1521-3757
dc.identifier.issn0044-8249
dc.identifier.doi10.1002/ange.202006978
dc.identifier.urihttp://hdl.handle.net/10754/665028
dc.description.abstractOur conceived approach based on the directed assembly of functional metal–organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co4(ImDC)4(En)4]⋅9 H2O⋅1.5 DMF (ZSA-10) and [Co4(ImDC)4(En)4]⋅7 H2O (ZSA-11) (H3ImDC=4,5-imidazoledicarboxylic acid, En=ethylenediamine, DMF=N,N-dimethylformamide). The elected MOSs encompass both trans- and cis-coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.
dc.description.sponsorshipThe authors gratefully acknowledge the financial support from the National Natural Science Foundation of China (Nos. 21771078, 21671074, and 21621001), the 111 Project (B17020), the National Key Research and Development Program of China (2016YFB0701100). The authors also gratefully acknowledge financial support from King Abdullah University of Science and Technology (KAUST).
dc.publisherWiley
dc.relation.urlhttps://onlinelibrary.wiley.com/doi/abs/10.1002/ange.202006978
dc.rightsArchived with thanks to Angewandte Chemie
dc.titleQuest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal–Organic Squares via Directed Hydrogen Bonding
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalAngewandte Chemie
dc.rights.embargodate2021-07-14
dc.eprint.versionPost-print
dc.contributor.institutionState Key Laboratory of Inorganic Synthesis and Preparative Chemistry, College of Chemistry, Jilin University, Changchun, 130012, P. R. China
kaust.personLi, Jiantang
kaust.personEddaoudi, Mohamed
dc.date.accepted2020-07-13
dc.identifier.eid2-s2.0-85089899108
dc.date.published-online2020-08-26
dc.date.published-print2020-10-26


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