Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids
dc.contributor.author | Knebel, Alexander | |
dc.contributor.author | Bavykina, Anastasiya | |
dc.contributor.author | Datta, Shuvo Jit | |
dc.contributor.author | Sundermann, Lion | |
dc.contributor.author | Garzon Tovar, Luis Carlos | |
dc.contributor.author | Lebedev, Yury | |
dc.contributor.author | Durini, Sara | |
dc.contributor.author | Ahmad, Rafia | |
dc.contributor.author | Kozlov, Sergey | |
dc.contributor.author | Shterk, Genrikh | |
dc.contributor.author | Karunakaran, Madhavan | |
dc.contributor.author | Carja, Ionela-Daniela | |
dc.contributor.author | Simic, Dino | |
dc.contributor.author | Weilert, Irina | |
dc.contributor.author | Klüppel, Manfred | |
dc.contributor.author | Giese, Ulrich | |
dc.contributor.author | Cavallo, Luigi | |
dc.contributor.author | Rueping, Magnus | |
dc.contributor.author | Eddaoudi, Mohamed | |
dc.contributor.author | Caro, Jürgen | |
dc.contributor.author | Gascon, Jorge | |
dc.date.accessioned | 2020-08-13T07:02:34Z | |
dc.date.available | 2020-08-13T07:02:34Z | |
dc.date.issued | 2020-08-10 | |
dc.date.submitted | 2019-02-02 | |
dc.identifier.citation | Knebel, A., Bavykina, A., Datta, S. J., Sundermann, L., Garzon-Tovar, L., Lebedev, Y., … Gascon, J. (2020). Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids. Nature Materials. doi:10.1038/s41563-020-0764-y | |
dc.identifier.issn | 1476-1122 | |
dc.identifier.issn | 1476-4660 | |
dc.identifier.pmid | 32778813 | |
dc.identifier.doi | 10.1038/s41563-020-0764-y | |
dc.identifier.uri | http://hdl.handle.net/10754/664580 | |
dc.description.abstract | The combination of well-defined molecular cavities and chemical functionality makes crystalline porous solids attractive for a great number of technological applications, from catalysis to gas separation. However, in contrast to other widely applied synthetic solids such as polymers, the lack of processability of crystalline extended solids hampers their application. In this work, we demonstrate that metal-organic frameworks, a type of highly crystalline porous solid, can be made solution processable via outer surface functionalization using N-heterocyclic carbene ligands. Selective outer surface functionalization of relatively large nanoparticles (250 nm) of the well-known zeolitic imidazolate framework ZIF-67 allows for the stabilization of processable dispersions exhibiting permanent porosity. The resulting type III porous liquids can either be directly deployed as liquid adsorbents or be co-processed with state-of-the-art polymers to yield highly loaded mixed matrix membranes with excellent mechanical properties and an outstanding performance in the challenging separation of propylene from propane. We anticipate that this approach can be extended to other metal-organic frameworks and other applications. | |
dc.description.sponsorship | L.S., A.K. and J.C. acknowledge support by the Deutsche Forschungsgemeinschaft in the priority program SPP 1928 COORNETs (Coordination Networks: Building Block for Functional Systems), grant no. CA 147/20-1 (J.C.). R.A., S.K and L.C. acknowledge the Supercomputing Laboratory at KAUST for computational resources (Cray XC40, ShaheenII). We thank P. M. Bhatt for helping with the propylene/propane adsorption kinetic study. King Abdullah University of Science and Technology is acknowledged for financial support. | |
dc.publisher | Springer Science and Business Media LLC | |
dc.relation.url | http://www.nature.com/articles/s41563-020-0764-y | |
dc.rights | Archived with thanks to Nature Materials | |
dc.title | Solution processable metal–organic frameworks for mixed matrix membranes using porous liquids | |
dc.type | Article | |
dc.contributor.department | Advanced Catalytic Materials, KAUST Catalysis Center, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia. | |
dc.contributor.department | Advanced Membranes and Porous Materials Research Center | |
dc.contributor.department | Chemical Engineering Program | |
dc.contributor.department | Chemical Science | |
dc.contributor.department | Chemical Science Program | |
dc.contributor.department | Functional Materials Design, Discovery and Development (FMD3) | |
dc.contributor.department | Functional Materials Design, Discovery and Development, Advanced Membranes & Porous Materials Center, King Abdullah University of Science and Technology, Thuwal, Saudi Arabia. | |
dc.contributor.department | KAUST Catalysis Center (KCC) | |
dc.contributor.department | Physical Science and Engineering (PSE) Division | |
dc.identifier.journal | Nature Materials | |
dc.rights.embargodate | 2021-02-10 | |
dc.eprint.version | Post-print | |
dc.contributor.institution | Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Hannover, Germany. | |
dc.contributor.institution | Deutsches Institut für Kautschuktechnologie e. V.,Hannover, Germany. | |
dc.contributor.institution | School of Chemistry and Chemical Engineering, South China University of Technology, Guangzhou, China. | |
kaust.person | Knebel, Alexander | |
kaust.person | Bavykina, Anastasiya | |
kaust.person | Datta, Shuvo Jit | |
kaust.person | Garzon Tovar, Luis Carlos | |
kaust.person | Lebedev, Yury | |
kaust.person | Durini, Sara | |
kaust.person | Ahmad, Rafia | |
kaust.person | Kozlov, Sergey | |
kaust.person | Shterk, Genrikh | |
kaust.person | Karunakaran, Madhavan | |
kaust.person | Carja, Ionela-Daniela | |
kaust.person | Cavallo, Luigi | |
kaust.person | Rueping, Magnus | |
kaust.person | Eddaoudi, Mohamed | |
kaust.person | Gascon, Jorge | |
dc.date.accepted | 2020-07-10 | |
refterms.dateFOA | 2020-08-13T13:07:30Z | |
kaust.acknowledged.supportUnit | Cray XC40 | |
kaust.acknowledged.supportUnit | Shaheen | |
kaust.acknowledged.supportUnit | Supercomputing Laboratory at KAUST | |
dc.date.published-online | 2020-08-10 | |
dc.date.published-print | 2020-12 |
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