Show simple item record

Methanol as the Hydrogen Source in the Selective Transfer Hydrogenation of Alkynes Enabled by a Manganese Pincer Complex

dc.contributor.authorSklyaruk, Jan
dc.contributor.authorZubar, Viktoriia
dc.contributor.authorBorghs, Jannik C.
dc.contributor.authorRueping, Magnus
dc.date.accessioned2020-08-09T08:46:18Z
dc.date.available2020-08-09T08:46:18Z
dc.date.issued2020-07-28
dc.identifier.citationSklyaruk, J., Zubar, V., Borghs, J. C., & Rueping, M. (2020). Methanol as the Hydrogen Source in the Selective Transfer Hydrogenation of Alkynes Enabled by a Manganese Pincer Complex. Organic Letters. doi:10.1021/acs.orglett.0c02151
dc.identifier.issn1523-7060
dc.identifier.issn1523-7052
dc.identifier.doi10.1021/acs.orglett.0c02151
dc.identifier.urihttp://hdl.handle.net/10754/664515
dc.description.abstractThe first base metal-catalyzed transfer hydrogenation of alkynes with methanol is described. An air and moisture stable manganese pincer complex catalyzes the reduction of a variety of different alkynes to the corresponding (Z)-olefins in high yields. The reaction is stereo- and chemoselective and scalable.
dc.description.sponsorshipJ.S. thanks the VCI (Verband der Chemischen Industrie) for the Chemiefonds-Stipendium. J.C.B. acknowledges the DBU (Deutsche Bundesstiftung Umwelt) for the doctoral fellowship. This work was financially supported by the King Abdullah University of Science and Technology (KAUST), Saudi Arabia, Office of Sponsored Research (FCC/1/1974).
dc.publisherAmerican Chemical Society (ACS)
dc.relation.urlhttps://pubs.acs.org/doi/10.1021/acs.orglett.0c02151
dc.rightsThis document is the Accepted Manuscript version of a Published Work that appeared in final form in Organic Letters, copyright © American Chemical Society after peer review and technical editing by the publisher. To access the final edited and published work see https://pubs.acs.org/doi/10.1021/acs.orglett.0c02151.
dc.titleMethanol as the Hydrogen Source in the Selective Transfer Hydrogenation of Alkynes Enabled by a Manganese Pincer Complex
dc.typeArticle
dc.contributor.departmentChemical Science Program
dc.contributor.departmentKAUST Catalysis Center (KCC)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalOrganic Letters
dc.rights.embargodate2021-07-28
dc.eprint.versionPost-print
dc.contributor.institutionInstitute of Organic Chemistry, RWTH Aachen University, Landoltweg 1, 52074 Aachen, Germany.
kaust.personZubar, Viktoriia
kaust.personRueping, Magnus
refterms.dateFOA2020-08-09T10:08:58Z
kaust.acknowledged.supportUnitOffice of Sponsored Research
dc.date.published-online2020-07-28
dc.date.published-print2020-08-07


Files in this item

Thumbnail
Name:
Manuscript_revised.pdf
Size:
517.7Kb
Format:
PDF
Description:
Accepted manuscript
Download

This item appears in the following Collection(s)

Show simple item record