Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Liu, Yunling; Li, Jiantang; Kan, Liang; Li, Jiyang; Eddaoudi, Mohamed

dc.contributor.author	Liu, Yunling
dc.contributor.author	Li, Jiantang
dc.contributor.author	Kan, Liang
dc.contributor.author	Li, Jiyang
dc.contributor.author	Eddaoudi, Mohamed
dc.date.accessioned	2020-07-16T13:11:10Z
dc.date.available	2020-07-16T13:11:10Z
dc.date.issued	2020-08-26
dc.date.submitted	2020-05-14
dc.identifier.citation	Liu, Y., Li, J., Kan, L., Li, J., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie International Edition. doi:10.1002/anie.202006978
dc.identifier.issn	1433-7851
dc.identifier.pmid	32662153
dc.identifier.doi	10.1002/anie.202006978
dc.identifier.uri	http://hdl.handle.net/10754/664243
dc.description.abstract	Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.
dc.publisher	Wiley
dc.relation.url	https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978
dc.rights	Archived with thanks to Angewandte Chemie (International ed. in English)
dc.title	Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.
dc.type	Article
dc.contributor.department	Advanced Membranes and Porous Materials Research Center
dc.contributor.department	Chemical Science Program
dc.contributor.department	Functional Materials Design, Discovery and Development (FMD3)
dc.contributor.department	Physical Science and Engineering (PSE) Division
dc.identifier.journal	Angewandte Chemie
dc.rights.embargodate	2021-07-15
dc.eprint.version	Post-print
dc.contributor.institution	Jilin UniversityState Key Laboratory of Inorganic Synthesis and Preparative Chemistry 2699 Qianjin Street 130012 Changchun CHINA
dc.contributor.institution	Jilin UniversityCollege of Chemistry CHINA
kaust.person	Eddaoudi, Mohamed
dc.date.accepted	2020-07-13
dc.relation.issupplementedby	DOI:10.5517/ccdc.csd.cc1zzc3f
dc.relation.issupplementedby	DOI:10.5517/ccdc.csd.cc1zzc5h
dc.relation.issupplementedby	DOI:10.5517/ccdc.csd.cc1zzc4g
refterms.dateFOA	2020-07-16T13:12:36Z
display.relations	<b>Is Supplemented By:</b><br/> <ul><li><i>[Dataset]</i> <br/> Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). <i>CCDC 1846425: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC3F. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1zzc3f" >10.5517/ccdc.csd.cc1zzc3f</a> HANDLE: <a href="http://hdl.handle.net/10754/665908">10754/665908</a></li><li><i>[Dataset]</i> <br/> Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). <i>CCDC 1846427: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC5H. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1zzc5h" >10.5517/ccdc.csd.cc1zzc5h</a> HANDLE: <a href="http://hdl.handle.net/10754/665909">10754/665909</a></li><li><i>[Dataset]</i> <br/> Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). <i>CCDC 1846426: Experimental Crystal Structure Determination</i> [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC4G. DOI: <a href="https://doi.org/10.5517/ccdc.csd.cc1zzc4g" >10.5517/ccdc.csd.cc1zzc4g</a> HANDLE: <a href="http://hdl.handle.net/10754/665911">10754/665911</a></li></ul>
dc.date.published-online	2020-08-26
dc.date.published-print	2020-10-26