Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

Thumbnail
Name:
Quest_anie.202006978.pdf
Size:
4.159Mb
Format:
PDF
Description:
Accepted manuscript
Embargo End Date:
2021-07-15
Download
Type
Article
Authors
Liu, Yunling
Li, Jiantang
Kan, Liang
Li, Jiyang
Eddaoudi, Mohamed cc
KAUST Department
Advanced Membranes and Porous Materials Research Center
Chemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2020-08-26
Online Publication Date
2020-08-26
Print Publication Date
2020-10-26
Embargo End Date
2021-07-15
Submitted Date
2020-05-14
Permanent link to this record
http://hdl.handle.net/10754/664243

Metadata
Show full item record
Abstract
Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.
Citation
Liu, Y., Li, J., Kan, L., Li, J., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie International Edition. doi:10.1002/anie.202006978
Publisher
Wiley
Journal
Angewandte Chemie (International ed. in English)
DOI
10.1002/anie.202006978
PubMed ID
32662153
Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978
Relations
Is Supplemented By:
  • [Dataset]
    Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846425: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC3F. DOI: 10.5517/ccdc.csd.cc1zzc3f HANDLE: 10754/665908
  • [Dataset]
    Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846427: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC5H. DOI: 10.5517/ccdc.csd.cc1zzc5h HANDLE: 10754/665909
  • [Dataset]
    Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846426: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC4G. DOI: 10.5517/ccdc.csd.cc1zzc4g HANDLE: 10754/665911
Collections
Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program