• Login
    View Item 
    •   Home
    • Research
    • Articles
    • View Item
    •   Home
    • Research
    • Articles
    • View Item
    JavaScript is disabled for your browser. Some features of this site may not work without it.

    Browse

    All of KAUSTCommunitiesIssue DateSubmit DateThis CollectionIssue DateSubmit Date

    My Account

    Login

    Quick Links

    Open Access PolicyORCID LibguidePlumX LibguideSubmit an Item

    Statistics

    Display statistics

    Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.

    • CSV
    • RefMan
    • EndNote
    • BibTex
    • RefWorks
    Thumbnail
    Name:
    Quest_anie.202006978.pdf
    Size:
    4.159Mb
    Format:
    PDF
    Description:
    Accepted manuscript
    Embargo End Date:
    2021-07-15
    Download
    Type
    Article
    Authors
    Liu, Yunling
    Li, Jiantang
    Kan, Liang
    Li, Jiyang
    Eddaoudi, Mohamed cc
    KAUST Department
    Advanced Membranes and Porous Materials Research Center
    Chemical Science Program
    Functional Materials Design, Discovery and Development (FMD3)
    Physical Science and Engineering (PSE) Division
    Date
    2020-08-26
    Online Publication Date
    2020-08-26
    Print Publication Date
    2020-10-26
    Embargo End Date
    2021-07-15
    Submitted Date
    2020-05-14
    Permanent link to this record
    http://hdl.handle.net/10754/664243
    
    Metadata
    Show full item record
    Abstract
    Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.
    Citation
    Liu, Y., Li, J., Kan, L., Li, J., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie International Edition. doi:10.1002/anie.202006978
    Publisher
    Wiley
    Journal
    Angewandte Chemie (International ed. in English)
    DOI
    10.1002/anie.202006978
    PubMed ID
    32662153
    Additional Links
    https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978
    Relations
    Is Supplemented By:
    • [Dataset]
      Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846425: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC3F. DOI: 10.5517/ccdc.csd.cc1zzc3f HANDLE: 10754/665908
    • [Dataset]
      Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846427: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC5H. DOI: 10.5517/ccdc.csd.cc1zzc5h HANDLE: 10754/665909
    • [Dataset]
      Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846426: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC4G. DOI: 10.5517/ccdc.csd.cc1zzc4g HANDLE: 10754/665911
    ae974a485f413a2113503eed53cd6c53
    10.1002/anie.202006978
    Scopus Count
    Collections
    Articles; Advanced Membranes and Porous Materials Research Center; Physical Science and Engineering (PSE) Division; Functional Materials Design, Discovery and Development (FMD3); Chemical Science Program

    entitlement

    Related articles

    • Tuning Gas Adsorption Properties of Zeolite-like Supramolecular Assemblies with gis Topology via Functionalization of Isoreticular Metal-Organic Squares.
    • Authors: Wang S, Belmabkhout Y, Cairns AJ, Li G, Huo Q, Liu Y, Eddaoudi M
    • Issue date: 2017 Oct 4
    • From metal-organic squares to porous zeolite-like supramolecular assemblies.
    • Authors: Wang S, Zhao T, Li G, Wojtas L, Huo Q, Eddaoudi M, Liu Y
    • Issue date: 2010 Dec 29
    • Exceptional stability and high hydrogen uptake in hydrogen-bonded metal-organic cubes possessing ACO and AST zeolite-like topologies.
    • Authors: Sava DF, Kravtsov VCh, Eckert J, Eubank JF, Nouar F, Eddaoudi M
    • Issue date: 2009 Aug 5
    • Molecular building blocks approach to the assembly of zeolite-like metal-organic frameworks (ZMOFs) with extra-large cavities.
    • Authors: Liu Y, Kravtsov VCh, Larsen R, Eddaoudi M
    • Issue date: 2006 Apr 14
    • Zeolite-like metal-organic frameworks (ZMOFs) based on the directed assembly of finite metal-organic cubes (MOCs).
    • Authors: Alkordi MH, Brant JA, Wojtas L, Kravtsov VCh, Cairns AJ, Eddaoudi M
    • Issue date: 2009 Dec 16
    DSpace software copyright © 2002-2021  DuraSpace
    Quick Guide | Contact Us | Send Feedback
    Open Repository is a service hosted by 
    Atmire NV
     

    Export search results

    The export option will allow you to export the current search results of the entered query to a file. Different formats are available for download. To export the items, click on the button corresponding with the preferred download format.

    By default, clicking on the export buttons will result in a download of the allowed maximum amount of items. For anonymous users the allowed maximum amount is 50 search results.

    To select a subset of the search results, click "Selective Export" button and make a selection of the items you want to export. The amount of items that can be exported at once is similarly restricted as the full export.

    After making a selection, click one of the export format buttons. The amount of items that will be exported is indicated in the bubble next to export format.