Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.
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Accepted manuscript
Embargo End Date:
2021-07-15
Type
ArticleKAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2020-08-26Online Publication Date
2020-08-26Print Publication Date
2020-10-26Embargo End Date
2021-07-15Submitted Date
2020-05-14Permanent link to this record
http://hdl.handle.net/10754/664243
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Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.Citation
Liu, Y., Li, J., Kan, L., Li, J., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie International Edition. doi:10.1002/anie.202006978Publisher
WileyPubMed ID
32662153Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978Relations
Is Supplemented By:- [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846425: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC3F. DOI: 10.5517/ccdc.csd.cc1zzc3f HANDLE: 10754/665908 - [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846427: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC5H. DOI: 10.5517/ccdc.csd.cc1zzc5h HANDLE: 10754/665909 - [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846426: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC4G. DOI: 10.5517/ccdc.csd.cc1zzc4g HANDLE: 10754/665911
ae974a485f413a2113503eed53cd6c53
10.1002/anie.202006978
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