Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding.
Type
Article
KAUST Department
Advanced Membranes and Porous Materials Research CenterChemical Science Program
Functional Materials Design, Discovery and Development (FMD3)
Physical Science and Engineering (PSE) Division
Date
2020-08-26Online Publication Date
2020-08-26Print Publication Date
2020-10-26Submitted Date
2020-05-14Permanent link to this record
http://hdl.handle.net/10754/664243Metadata
Show full item recordAbstract
Our conceived approach based on the directed assembly of functional metal-organic squares (MOSs), 4-membered ring (4MR) building units, permitted the construction of two novel zeolite-like supramolecular assemblies (ZSAs), namely [Co 4 (ImDC) 4 (En) 4 ]·9H 2 O·1.5DMF ( ZSA-10 ) and [Co 4 (ImDC) 4 (En) 4 ]·7H 2 O ( ZSA-11 ) (H 3 ImDC = 4,5-imidazoledicarboxylic acid, En = ethylenediamine, DMF = N,N-dimethylformamide). The elected MOSs encompass both trans - and cis -coordinated nodes, offering complementary peripheral functional groups for their directed assembly into zeolite-like topologies via supramolecular hydrogen bonding interactions. Distinctly, ZSA-10 possesses the underling MER zeolite topology and is the only pure MER framework material (without any supporting templates) exhibiting permanent porosity up to now. ZSA-11 has the underlying ABW topology together with one type of narrow channel.Citation
Liu, Y., Li, J., Kan, L., Li, J., & Eddaoudi, M. (2020). Quest for Zeolite-like Supramolecular Assemblies: Self-Assembly of Metal-Organic Squares via Directed Hydrogen Bonding. Angewandte Chemie International Edition. doi:10.1002/anie.202006978Publisher
WileyJournal
Angewandte ChemiePubMed ID
32662153Additional Links
https://onlinelibrary.wiley.com/doi/abs/10.1002/anie.202006978Relations
Is Supplemented By:- [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846425: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC3F. DOI: 10.5517/ccdc.csd.cc1zzc3f HANDLE: 10754/665908 - [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846427: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC5H. DOI: 10.5517/ccdc.csd.cc1zzc5h HANDLE: 10754/665909 - [Dataset]
Liu, Yunling, Li, Jiantang, Kan, Liang, Li, Jiyang, & Eddaoudi, Mohamed. (2020). CCDC 1846426: Experimental Crystal Structure Determination [Data set]. Cambridge Crystallographic Data Centre. https://doi.org/10.5517/CCDC.CSD.CC1ZZC4G. DOI: 10.5517/ccdc.csd.cc1zzc4g HANDLE: 10754/665911