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dc.contributor.authorBhatt, Prashant
dc.contributor.authorGuillerm, Vincent
dc.contributor.authorDatta, Shuvo Jit
dc.contributor.authorShkurenko, Aleksander
dc.contributor.authorEddaoudi, Mohamed
dc.date.accessioned2020-07-14T09:45:29Z
dc.date.available2020-07-14T09:45:29Z
dc.date.issued2020-07-09
dc.identifier.citationBhatt, P. M., Guillerm, V., Datta, S. J., Shkurenko, A., & Eddaoudi, M. (2020). Topology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study. Chem, 6(7), 1613–1633. doi:10.1016/j.chempr.2020.06.018
dc.identifier.issn2451-9294
dc.identifier.issn2451-9308
dc.identifier.doi10.1016/j.chempr.2020.06.018
dc.identifier.urihttp://hdl.handle.net/10754/664170
dc.description.abstractChemical separations are of prime industrial importance; however, they consume a large portion of total industrial energy. Credibly, adsorbent-based separation methods offer the prospective to drastically lessen the energy demand of conventional energy-intensive separation processes. Prominently, a special class of porous materials, namely metal-organic frameworks (MOFs), are reasonably positioned to address various demanding separations in an energy-efficient manner. Out of a myriad of possible topologies for the construction of MOFs, face-transitive nets affording a sole type of window, preferably defined by three- or four-membered rings, can be regarded as ideal blueprints for the construction of MOFs for targeted separations. Intricate separations by MOFs based on some of these topologies are discussed, highlighting the effect of appropriate pore aperture and channel size with prerequisite functional groups on their separation performance. MOFs based on face-transitive nets offer great potential as effective fillers for the construction of practical mixed-matrix membranes (MMMs) with improved separation properties over conventional polymeric membranes.
dc.description.sponsorshipThe authors thank King Abdullah University of Science and Technology for funding and support. M.E. proposed the topic of perspective. M.E. P.B, V.G. S.D. and A.S. reviewed the literature and wrote the manuscript.
dc.publisherElsevier BV
dc.relation.urlhttps://linkinghub.elsevier.com/retrieve/pii/S2451929420302990
dc.rightsNOTICE: this is the author’s version of a work that was accepted for publication in Chem. Changes resulting from the publishing process, such as peer review, editing, corrections, structural formatting, and other quality control mechanisms may not be reflected in this document. Changes may have been made to this work since it was submitted for publication. A definitive version was subsequently published in Chem, [6, 7, (2020-07-09)] DOI: 10.1016/j.chempr.2020.06.018 . © 2020. This manuscript version is made available under the CC-BY-NC-ND 4.0 license http://creativecommons.org/licenses/by-nc-nd/4.0/
dc.titleTopology Meets Reticular Chemistry for Chemical Separations: MOFs as a Case Study
dc.typeArticle
dc.contributor.departmentAdvanced Membranes and Porous Materials Research Center
dc.contributor.departmentChemical Science Program
dc.contributor.departmentFunctional Materials Design, Discovery and Development (FMD3)
dc.contributor.departmentPhysical Science and Engineering (PSE) Division
dc.identifier.journalChem
dc.rights.embargodate2021-07-09
dc.eprint.versionPost-print
dc.identifier.volume6
dc.identifier.issue7
dc.identifier.pages1613-1633
kaust.personBhatt, Prashant
kaust.personGuillerm, Vincent
kaust.personDatta, Shuvo Jit
kaust.personShkurenko, Aleksander
kaust.personEddaoudi, Mohamed
kaust.personEddaoudi, Mohamed
dc.identifier.eid2-s2.0-85087417389
dc.date.published-online2020-07-09
dc.date.published-print2020-07


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